BIS(4-NITROPHENYL) CARBONATE

BIS(4-NITROPHENYL) CARBONATE
  • CAS No.:5070-13-3
Other grades of this product :
BIS(4-NITROPHENYL) CARBONATE Basic information
Product Name:BIS(4-NITROPHENYL) CARBONATE
Synonyms:BIS(4-NITROPHENYL) CARBONATE;CARBONIC ACID BIS(4-NITROPHENYL) ESTER;BIS(P-NITROPHENYL) CARBONATE;4-NITROPHENYL CARBONATE;Bis(4-nitrophenyl) carbonate reference substance;Bis(4-nitrophenyl) carbonate ,97%;p,p'-Dinitrodiphenylcarbonate;NPC [Bis(4-nitrophenyl)carbonate]
CAS:5070-13-3
MF:C13H8N2O7
MW:304.21
EINECS:225-775-4
Product Categories:Industrial/Fine Chemicals
Mol File:5070-13-3.mol
BIS(4-NITROPHENYL) CARBONATE Chemical Properties
Melting point 136-139 °C(lit.)
Boiling point 475.9±30.0 °C(Predicted)
density 1.501±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in chloroform and tetrahydrofuran.
form Liquid
color Clear slightly yellow or greenish to brown
Sensitive Moisture Sensitive
BRN 1892897
InChIKeyACBQROXDOHKANW-UHFFFAOYSA-N
CAS DataBase Reference5070-13-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-36
WGK Germany 3
10-21
HS Code 29209090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BIS(4-NITROPHENYL) CARBONATE Usage And Synthesis
Chemical Propertieswhite to pale yellow or beige powder
UsesBis(4-nitrophenyl) carbonate is used as a reagent for preparation of symmetrical and unsymmetrical urea and 4-nitrophenyl esters of N-protected amino acids. It acts as a peptide coupling reagent. It finds application as a reagent for the preparation of carbamate linked cytosines.
Purification MethodsDissolve the carbonate in CHCl3, wash it with 2N NaOH (3 x) and once with conc HCl, dry (Na2SO4), evaporate and crystallise the residue from toluene (authors say prisms from 15 volumes of *benzene). [Glatthard & Matter Helv Chim Acta 46 795 1963, Beilstein 6 III 820.]

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