| Ethyltriphenylphosphonium iodide Basic information |
| Product Name: | Ethyltriphenylphosphonium iodide |
| Synonyms: | Phosphonium, ethyltriphenyl-, iodide (1:1);EPJ;ETPPI;ETHYLTRIPHENYLPHOSPHONIUM IODIDE;ETHYLTRIPHENYLPHOSPHONIUM IODIDE 99+%;Ethyltriphenylphosphonium iodide, 95 %;ETHYLTRIPHENYHLPHOSPHONIUM IODIDE;ETPPI: Ethyltriphenylphosphonium Iodide |
| CAS: | 4736-60-1 |
| MF: | C20H20IP |
| MW: | 418.251031 |
| EINECS: | 225-245-2 |
| Product Categories: | Pharmaceutical Intermediates;Phosphonium Compounds;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction;Greener Alternatives: Catalysis;C-C Bond Formation;Olefination;Wittig Reagents;Phase Transfer Catalysts;Phosphonium SaltsC-C Bond Formation |
| Mol File: | 4736-60-1.mol |
| Ethyltriphenylphosphonium iodide Chemical Properties |
| Melting point | 164-168 °C(lit.) |
| Boiling point | 337 °C |
| density | 1.500 |
| vapor pressure | 0Pa at 25℃ |
| Fp | 226 °C |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Acetone, Chloroform, Dichloromethane, Methanol |
| form | Powder |
| color | Yellow |
| Water Solubility | slightly soluble |
| Sensitive | Light Sensitive & Hygroscopic |
| BRN | 3659323 |
| InChIKey | SLAFUPJSGFVWPP-UHFFFAOYSA-M |
| LogP | 0.324 |
| CAS DataBase Reference | 4736-60-1(CAS DataBase Reference) |
| EPA Substance Registry System | Phosphonium, ethyltriphenyl-, iodide (4736-60-1) |
| Safety Information |
| Hazard Codes | T,Xn |
| Risk Statements | 25-36/38-21-36/37/38-20/21/22 |
| Safety Statements | 45-36/37/39-28A-26-36 |
| RIDADR | UN 2811 6.1/PG 3 |
| WGK Germany | 3 |
| RTECS | TA2312000 |
| F | 3-8-10 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | III |
| HS Code | 29310095 |
| MSDS Information |
| Provider | Language |
|---|---|
| Ethyltriphenylphosphonium iodide | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Ethyltriphenylphosphonium iodide Usage And Synthesis |
| Chemical Properties | Ethyltriphenylphosphonium iodide is white to slightly yellowish crystalline powder |
| Uses | Ethyltriphenylphosphonium iodide is used as a Wittig reagent and phase transfer catalyst in organic synthesis. It can also be used in asymmetric hydrogenation and to make Bismuth(III) polynuclear complexes. |
| Uses | Ethyltriphenylphosphonium iodide is involved in synthesis of diarylmethine derivatives, phosphonium salts, and bismuth(III) polynuclear halide complexes, asymmetric hydrogenation. |
| Flammability and Explosibility | Notclassified |
| Ethyltriphenylphosphonium iodide Preparation Products And Raw materials |
| Preparation Products | [1S-[1alpha,2alpha(Z),4alpha]]-2-methyl-5-(2-methyl-3-methylenebicyclo[2.2.1]hept-2-yl)-2-penten-1-ol-->DIPHENYLETHYLPHOSPHINE OXIDE |
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