2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE

2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
  • CAS No.:24720-64-7
Other grades of this product :
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Basic information
Product Name:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE
Synonyms:2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE;2-(triphenylphosphoranylidene)propionaldehyde, 98 %;2-(triphenylphosphoranylidene);2-(TRIPHENYLPHOSPHOR;1-Formylethylidenetriphenylphosphorane;2-(Triphenylphosphoranylidene)propanal;2-(triphenyl-l5-phosphanylidene)propanal;2-(Triphenylphosphoranylidene)propionaldehyde 98%
CAS:24720-64-7
MF:C21H19OP
MW:318.35
EINECS:
Product Categories:Aldehydes;Building Blocks;C13-C60;Carbonyl Compounds;C-C Bond Formation;Chemical Synthesis;C-C Bond Formation;Olefination;Wittig Reagents;Organic Building Blocks;Synthetic Reagents;Wittig Reagents
Mol File:24720-64-7.mol
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Chemical Properties
Melting point 219-221 °C (lit.)
Boiling point 478.5±28.0 °C(Predicted)
density 1.14±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Low Melting Solid
color White to pink to brown
CAS DataBase Reference24720-64-7
Safety Information
Risk Statements 22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Usage And Synthesis
Chemical PropertiesWhite to light beige crystalline powder
UsesReactant for:• ;Preparation of acitretin analogs with antitumor activity1• ;Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration2• ;Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination3• ;Wittig reactions4• ;Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents5• ;Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors
Uses2-(Triphenylphosphoranylidene)propionaldehyde is a reagent used in the asymmetric synthesis of hispidanin A via oxidative alkoxylation and stereoselective Diels-Alder reaction. Also acts as a reagent in the stereoselective synthesis of 10-epi-tirandamycin E.
UsesReactant for:
  • Preparation of acitretin analogs with antitumor activity
  • Stereoselective synthesis of essential building blocks of phorboxazole A via hetero Diels-Alder and stereoselective hetero-Michael addition/equilibration
  • Preparation of C1-C14 fragment of sarcoglaucol-16-one via Z-selective ando-type Horner-Wadsworth-Emmons olefination
  • Wittig reactions
  • Synthesis of ring-expanded and epothilone-hybridized macrosphelide analogs as apoptosis-inducing agents
  • Preparation of phosphonic acid-containing analogs of mycophenolic acid as inhibitors of IMPDH
2-(TRIPHENYLPHOSPHORANYLIDENE)PROPIONALDEHYDE Preparation Products And Raw materials

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