Other grades of this product :
| [Ir(dtbbpy)(ppy)2][PF6] Basic information | | Reaction |
| Product Name: | [Ir(dtbbpy)(ppy)2][PF6] | | Synonyms: | [Ir(dtbbpy)(ppy)2][PF6];(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;[Ir(dtbbpy)(ppy);Ir(ppy)2(dtbbpy)PF6;(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%;[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate | | CAS: | 676525-77-2 | | MF: | C40H40F6IrN4P | | MW: | 913.97 | | EINECS: | | Product Categories: | | Mol File: | 676525-77-2.mol |
| [Ir(dtbbpy)(ppy)2][PF6] Chemical Properties |
| storage temp. | 2-8°C | | form | crystal | | color | yellow | | λmax | 380nm(CH2Cl2)(lit.) |
| Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | TSCA | No |
| [Ir(dtbbpy)(ppy)2][PF6] Usage And Synthesis |
| Reaction |
- This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
- Numerous uses of this photoredox catalyst are reported
| | Uses | [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:- Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
- Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
- Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
- Aryl-alkyl C?C reductive cross-coupling reactions.
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| [Ir(dtbbpy)(ppy)2][PF6] Preparation Products And Raw materials |
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![[Ir(dtbbpy)(ppy)2][PF6]](/img/676525-77-2.jpg "[Ir(dtbbpy)(ppy)2][PF6]")
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