(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • CAS No.:173831-50-0
Other grades of this product :
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Basic information
Reaction
Product Name:(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
Synonyms:(R)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAP&;(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl,98%;2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE;2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE;(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(S)-(-)-2,2'-BIS(METHOXYMETHOXY)-1,1-BINAPHTHALENE
CAS:173831-50-0
MF:C24H22O4
MW:374.43
EINECS:
Product Categories:BINOL Series;Chiral Oxygen;BINOLs;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;Aromatics;Other Ligands;Catalysis and Inorganic Chemistry;Chemical Synthesis;Chiral Reagents;Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:173831-50-0.mol
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Chemical Properties
Melting point 92-96 °C(lit.)
alpha +85° (c 0.22, CHCl3)
Boiling point 477.8±45.0 °C(Predicted)
density 1.182±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Toluene
form Powder
color white
optical activity[α]20/D +92°, c = 1% in chloroform
Safety Information
Hazard Codes Xi,N
Risk Statements 41-50/53
Safety Statements 26-39-60-61-36/39-25
RIDADR UN 3077 9/PG 3
WGK Germany 3
HS Code 29093090
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Usage And Synthesis
ReactionStarting material for the preparation of a variety of 3,3'-substituted binaphthols.
Chemical PropertiesColorless solid
UsesAn intermediate in the symmetric synthesis of BINOL-terpyridine ligands.
Uses3- or 3,3′-di-substituted products can be obtained easily via ortho-metallation and subsequent treatment with an electrophile to give the corresponding BINOL derivatives.
(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL Preparation Products And Raw materials
Raw materialsHypochlorous acid, methoxymethyl ester (9CI)-->(S)-(-)-1,1'-Bi-2-naphthol-->2-Naphthol-->1,1'-Bi-2-naphthol-->Chloromethyl methyl ether

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