Zirconium hydroxide

Zirconium hydroxide
  • CAS No.:14475-63-9

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Zirconium hydroxide Basic information
Product Name:Zirconium hydroxide
Synonyms:zirconiumhydroxide(zr(oh)4);ZIRCONIUM HYDROXIDE;ZIRCONIUM(IV) HYDROXIDE;Zirconium(IV) hydroxide 97%;Zirconium(2+) hydroxide (1:2);Zirconium hydroxide, hydrate;XZO-632/03;Zirconic acid
CAS:14475-63-9
MF:H4O4Zr
MW:159.25
EINECS:238-472-7
Product Categories:Metal and Ceramic Science;Salts;Zirconium Salts
Mol File:14475-63-9.mol
Zirconium hydroxide Chemical Properties
density 3.25
form white amorphous powder
Water Solubility insoluble H2O and alkalies; soluble mineral acids [MER06] [HAW93]
Merck 13,10230
InChIKeyHAIMOVORXAUUQK-UHFFFAOYSA-J
CAS DataBase Reference14475-63-9(CAS DataBase Reference)
EPA Substance Registry SystemZirconium hydroxide (Zr(OH)4), (T-4)- (14475-63-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
Zirconium hydroxide Usage And Synthesis
DescriptionZirconium hydroxide, often called hydrous zirconia is a water-insoluble, slightly alkaline amphoteric oxide, which is widely used in the preparation of pigments, glass, dyes and other industries, and is also an important intermediate for the preparation of other zirconium compounds.
Chemical PropertiesWhite, bulky, amorphous powder.Decomposes to ZrO2 at 550C. Soluble in dilute mineral acids; insoluble in water and alkalies.
UsesZirconium hydroxide is used in the pigment, dye, and glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts.
PreparationZirconium hydride precipitates on adding sodium hydroxide solution to an aqueous solution of zirconium salt:ZrCl4 (aq)+ 4NaOH(aq) → Zr(OH)4 (s) + 4NaCl(aq)
ReactionsWhen heated at 550°C the hydroxide decomposes to oxide:Zr(OH)4 → ZrO2 + 2H2OReacitons with mineral acids followed by crystallization forms corresponding zirconium salts. Thus hydrochloric, sulfuric, and phosphoric acids yield chloride, sulfate and phosphate of zirconium respectively.
Properties and ApplicationsZirconium Hydroxide is a highly water insoluble crystalline Zirconium source for uses compatible with higher (basic) pH environments. 
Zirconium hydroxide Preparation Products And Raw materials
Raw materialsOxygen
Preparation ProductsZirconium dioxide-->Zirconyl chloride octahydrate-->water proofing agent MWZ-->water proofing agent WDC-108

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