(1S,2R)-2-Amino-1,2-diphenylethanol

(1S,2R)-2-Amino-1,2-diphenylethanol
  • CAS No.:23364-44-5
Other grades of this product :
(1S,2R)-2-Amino-1,2-diphenylethanol Basic information
Reaction
Product Name:(1S,2R)-2-Amino-1,2-diphenylethanol
Synonyms:(1S,2R)-(-)-2-AMINO-1,2-DIPHENYLETHANOL;(1S,2R)-(+)-2-AMINO-1,2-DIPHENYLETHANOL;(1S,2R)-2-AMINO-1,2-DIPHENYLETHANOL;(1S,2R)-(+)-DIPHENYL-2-AMINOETHANOL;(1S,2R)-2-Amino-1,2-diphenylethanol,98%;(1S,2R)-(+)-2-Amino-1,2-diphenylethanol ,98% [ee:99%];(1R,2S)-1,2-Diphenyl-1-amino-2-hydroxyethane;(1S,2R)-2-Amino-1,2-
CAS:23364-44-5
MF:C14H15NO
MW:213.28
EINECS:628-513-0
Product Categories:Organic Building Blocks;Chiral Compound;chiral;Benzene derivatives;Amino Alcohols;Chiral Building Blocks;Chiral reagent;Amino Alcohols (Chiral);Chiral Building Blocks;for Resolution of Acids;Optical Resolution;Synthetic Organic Chemistry;Amino Alcohols & Deriv.;CHIRAL CHEMICALS;Chiral chemicals
Mol File:23364-44-5.mol
(1S,2R)-2-Amino-1,2-diphenylethanol Chemical Properties
Melting point 142-144 °C(lit.)
alpha 7 º (c=0.6, EtOH)
Boiling point 374.3±37.0 °C(Predicted)
density 1.148±0.06 g/cm3(Predicted)
refractive index 7 ° (C=0.6, EtOH)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility very faint turbidity in Methanol
pka11.70±0.45(Predicted)
form Crystalline Powder
color White to beige
optical activity[α]25/D +7.0°, c = 0.6 in ethanol
BRN 1212828
InChIKeyGEJJWYZZKKKSEV-KGLIPLIRSA-N
CAS DataBase Reference23364-44-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36
WGK Germany 3
9
HS Code 29221990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(1S,2R)-2-Amino-1,2-diphenylethanol Usage And Synthesis
Reaction
  1. Ligand used to make chiral oxaborolidines for the enantioselective alkynylation of aldehydes
  2. Ligand used in organoindium reagents for asymmetric Barbier-type allylations
  3. Ligand used in organoindium reagents for asymmetric Barbier-type propargylations
Chemical Propertieswhite to light yellow crystal powde
Uses(1S,2R)-(+)-2-Amino-1,2-diphenylethanol can be used:
  • To prepare vanadium(V) Schiff base complexes, which are used as catalysts in the oxidation of sulfides and olefins.
  • To prepare chiral selectors, which are immobilized on aminated silica gel, applicable as chiral stationary phase in HPLC.
  • To immobilize on the frame of α-zirconium phosphate to yield layered zirconium phosphonates, which are used in the heterogeneous catalysis.
  • As a chiral auxiliary in the preparation of homopropargylic alcohols from aliphatic and aromatic aldehydes.
(1S,2R)-2-Amino-1,2-diphenylethanol Preparation Products And Raw materials

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