4-Methylpiperidine

4-Methylpiperidine
  • CAS No.:626-58-4
Other grades of this product :
4-Methylpiperidine Basic information
Product Name:4-Methylpiperidine
Synonyms:LABOTEST-BB LTBB000596;HEXAHYDRO-G-PICOLINE;GAMMA-PIPECOLINE;4-METHYLPIPERIDINE;4-PIPECOLINE;4PPC;4-methyl-piperidin;4-pipecoline(gamma-)
CAS:626-58-4
MF:C6H13N
MW:99.17
EINECS:210-954-1
Product Categories:Chemical Synthesis;Heterocyclic Building Blocks;Piperidine;Building Blocks;C5 to C7;Piperidines
Mol File:626-58-4.mol
4-Methylpiperidine Chemical Properties
Melting point 4-5 °C
Boiling point 124 °C(lit.)
density 0.838 g/mL at 25 °C(lit.)
vapor pressure 16 hPa (20 °C)
refractive index n20/D 1.446(lit.)
Fp 45 °F
storage temp. Flammables area
solubility Chloroform
form Liquid
pkapK1:11.23(+1) (25°C,μ=0.5)
Specific Gravity0.838
color Clear slightly yellow
PH13 (100g/l, H2O, 20℃)
Water Solubility miscible
BRN 1083
CAS DataBase Reference626-58-4(CAS DataBase Reference)
NIST Chemistry ReferencePiperidine, 4-methyl-(626-58-4)
EPA Substance Registry SystemPiperidine, 4-methyl- (626-58-4)
Safety Information
Hazard Codes F,Xi,T
Risk Statements 11-36/37/38-36-20/21-10-61
Safety Statements 16-26-36-45-36/37-53
RIDADR UN 1993 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29333999
MSDS Information
ProviderLanguage
4-Methylpiperidine English
SigmaAldrich English
ACROS English
ALFA English
4-Methylpiperidine Usage And Synthesis
Chemical Propertiesclear slightly yellow liquid
Uses4-Methylpiperidine is used as a catalyst in the synthesis of stilbene derivatives as anti-malarial agents. It also serves as an anti-corrosive compound for iron.
Uses4-Methylpiperidine acts as a catalyst in the preparation of stilbene derivatives. It is used as an anti-corrosive compound for iron. It is also used in the synthesis of peptides to remove or deprotection of 9-fluorenylmethyloxycarbonyl (Fmoc) groups.
Purification MethodsPurify it via the hydrochloride (m 189o). It is freed from 3-methylpyridine by zone melting. The hydrobromide has m 173o(from butanone/*C6H6). [Beilstein 20 III/IV 1511, 20/4 V 116.]
4-Methylpiperidine Preparation Products And Raw materials
Preparation Products2-(4-METHYL-PIPERIDIN-1-YL)-ETHYLAMINE-->4-METHYLENEPIPERIDINE-->4-Methyl-1,2,3,6-tetrahydropyridine

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