(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl

(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
  • CAS No.:134484-36-9
Other grades of this product :
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Basic information
Reaction
Product Name:(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
Synonyms:(S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-MOP;(S)-MOP;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-(DIPHENYLPHOSPHINO)-2''-METHOXY-1,1''-BINAPHTHYL (S)-MOP;(S)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine;(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
CAS:134484-36-9
MF:C33H25OP
MW:468.52
EINECS:
Product Categories:Chiral Phosphine;API intermediates;Chiral Reagents
Mol File:134484-36-9.mol
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Chemical Properties
Melting point 175-179°C
alpha -67° ±2° (c 1, toluene)
Boiling point 584.1±38.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility almost transparency in Toluene
form Powder
color white
Sensitive air sensitive
Safety Information
MSDS Information
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Usage And Synthesis
Reaction
  1. Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
  2. Ligand for palladium-catalyzed asymmetric reduction of allylic esters.
  3. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes.
  4. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins.
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Preparation Products And Raw materials

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