Allyl Propyl Disulfide

Allyl Propyl Disulfide
  • CAS No.:2179-59-1
Other grades of this product :
Allyl Propyl Disulfide Basic information
Product Name:Allyl Propyl Disulfide
Synonyms:2-PROPENYL PROPYL DISULFIDE;ALLYL PROPYL DISULFIDE;ALLYL PROPYL DISULPHIDE;FEMA 4073;disulfide,2-propenylpropyl;disulfide,allylpropyl;disulfured’allyleetdepropyle;4,5-Dithia-1-octene
CAS:2179-59-1
MF:C6H12S2
MW:148.29
EINECS:218-550-7
Product Categories:sulfide Flavor
Mol File:2179-59-1.mol
Allyl Propyl Disulfide Chemical Properties
Melting point -15°C
Boiling point 69 °C / 16mmHg
density 0.99
refractive index 1.5160-1.5200
FEMA 4073 | ALLYL PROPYL DISULFIDE
Fp 56 °C
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Pale yellow oil
color Colorless to Light yellow to Light orange
Water Solubility Insoluble. <0.1 g/100 mL at 20 ºC
JECFA Number1700
CAS DataBase Reference2179-59-1(CAS DataBase Reference)
NIST Chemistry Reference2-propenyl propyl disulfide(2179-59-1)
EPA Substance Registry SystemAllyl propyl disulfide (2179-59-1)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26
RIDADR 1993
RTECS JO0350000
HazardClass 3.2
PackingGroup III
Hazardous Substances Data2179-59-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Allyl Propyl Disulfide English
Allyl Propyl Disulfide Usage And Synthesis
Chemical PropertiesAllyl propyl disulfi de is a pale yellow liquid with a pungent odor and is insoluble in water. It decomposes on burning, producing sulfur oxides, and it also gives off irritating or toxic fumes (or gases) in a fi re. It reacts with oxidants. Allyl propyl sulfi de is used as a synthetic fl avor and food additive. Allyl propyl disulfi de is the chief volatile component of onion oil as well as being a volatile component of chives and garlic.
Chemical PropertiesOnion oil is obtained by steam distillation of the crushed bulbs of the common onion, Allium cepa L. It is produced mainly in Mexico, China,and Egypt, and, in smaller quantities, also in Europe (France, Hungary) and is an amber-yellow to amber liquid with a strongly pungent, lasting, characteristic onion odor.d2525 1.050–1.135; n20D 1.5495–1.5695
Chemical PropertiesColorless to yellowish liquid; fruity, garlic aroma.
OccurrenceReported as the chief volatile constituent in onion oil and found in raw cabbage, chive, garlic oil, leek and onion.
Aroma threshold valuesHigh strength odor, sulfurous type; recommend smelling in a 0.10% solution or less.
Taste threshold valuesTaste like that of cooked onions.
General DescriptionClear pale yellow liquid with a pungent odor.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileAllyl Propyl Disulfide may react vigorously with strong oxidizing agents. Incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. May liberate hydrogen sulfide upon decomposition or reaction with an acid.
HazardEye and upper respiratory tract irritant.
Health HazardExposures to allyl propyl disulfi de are absorbed into the body by inhalation and by ingestion. It causes a burning sensation, cough, chest tightness, nausea, vomiting, irritation to the eyes, skin, and respiratory tract. Based on animal and human experimental data, allyl propyl sulfi de is regarded as an occupational skin sensitizer.
Fire HazardAllyl Propyl Disulfide is combustible.
Contact allergensWith allicin and diallyl sulfide, allylpropyldisulfide is one of the allergens in garlic (Allium sativum L.). See also Chap. 46.
Safety ProfileSkin irritant. When heated to decomposition it emits acrid smoke and irritating fumes
storageAllyl propyl disulfi de should be separated from oxidants.
PrecautionsDuring use/handling of allyl propyl disulfi de, occupational workers should use safety goggles or eye protection in combination with breathing protection and protective gloves. Many of the chemical reactions may result in a hazardous situation, i.e., generation of flammable or toxic chemicals, fi re or detonation.
Allyl Propyl Disulfide Preparation Products And Raw materials
Preparation ProductsETHYL METHYL DISULFIDE

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