2'-Bromoacetophenone

CAS No.：2142-69-0

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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2'-Bromoacetophenone Basic information

Product Name:	2'-Bromoacetophenone
Synonyms:	Acetophenone, o-bromo-;ETHANONE, 1-(2-BROMOPHENYL)-;AKOS BBS-00004325;1-(2-BROMOPHENYL)ETHANONE;1-(2-BROMOMPHENYL)ETHANONE;1-ACETYL-2-BROMOBENZENE;O-BROMOACETOPHENONE;O-BROMOPHENYL METHYL KETONE
CAS:	2142-69-0
MF:	C8H7BrO
MW:	199.04
EINECS:	218-398-1
Product Categories:	Building Blocks;C7 to C8;Acetophenone series;Chemical Synthesis;Ketones;Organic Building Blocks;Carbonyl Compounds;Aromatic Acetophenones & Derivatives (substituted);Benzene series;Adehydes, Acetals & Ketones;Bromine Compounds
Mol File:	2142-69-0.mol

2'-Bromoacetophenone Chemical Properties

Melting point	°C
Boiling point	116-117 °C (12 mmHg)
density	1.476 g/mL at 25 °C(lit.)
refractive index	n20/D 1.568(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
form	Liquid
Specific Gravity	1.476
color	Clear pale yellow to orange
Water Solubility	PRACTICALLY INSOLUBLE
BRN	1931534
InChIKey	PIMNFNXBTGPCIL-UHFFFAOYSA-N
CAS DataBase Reference	2142-69-0(CAS DataBase Reference)
NIST Chemistry Reference	Ethanone, 1-(2-bromophenyl)-(2142-69-0)

Safety Information

Hazard Codes	Xi,C
Risk Statements	36/37/38-34
Safety Statements	26-36-37/39-45-36/37/39
WGK Germany	3
Hazard Note	Irritant
HS Code	29147090

MSDS Information

Provider	Language
1-(2-Bromophenyl)ethanone	English
ACROS	English
SigmaAldrich	English
ALFA	English

2'-Bromoacetophenone Usage And Synthesis

Chemical Properties	Clear pale yellow to orange liquid
Uses	2-bromoacetophenone is employed in the selective derivatization of cytosine moieties for the determination of global DNA methylation by reversed phase high performance liquid chromatography with spectrofluorimetric detection.
Uses	2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.
General Description	2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

2'-Bromoacetophenone Preparation Products And Raw materials

Preparation Products

Methyl 2-bromobenzoate-->1-Bromo-2-(1,1-difluoroethyl)benzene-->1-PHENYL-1-PENTYNE-->ETHYL3-METHYL-2-INDOLECARBOXYLATE-->2-(2-Bromophenyl)-2-propanol-->1-BROMO-2-ETHYNYLBENZENE-->2-BROMO-5-NITROBENZOIC ACID-->Lonidamine

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