Methacrylic anhydride

Methacrylic anhydride
  • CAS No.:760-93-0
Other grades of this product :
Methacrylic anhydride Basic information
Product Name:Methacrylic anhydride
Synonyms:1-Methylacrylic anhydride;2-methyl-2-propenoicacianhydride;2-Propenoic acid, 2-methyl-, anhydride;2-Propenoicacid,2-methyl-,anhydride;Methylacrylic acid anhydride;Methacrylic acid anhydride;methacrylicacidanhydride;Methacryloyl anhydride
CAS:760-93-0
MF:C8H10O3
MW:154.17
EINECS:212-084-8
Product Categories:Organic acids;Carbonyl Compounds;Anhydride Monomers;Monomers;Carboxylic Acid Anhydrides;Organic Building Blocks;Polymer Science
Mol File:760-93-0.mol
Methacrylic anhydride Chemical Properties
Melting point -20°C
Boiling point 87 °C13 mm Hg(lit.)
density 1.04 g/mL at 20 °C
vapor pressure 90Pa at 20℃
refractive index n20/D 1.453(lit.)
Fp 184 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Miscible with ethanol and ether.
form clear liquid
color Colorless to Light yellow to Light orange
Water Solubility 98g/L at 20℃
Sensitive Moisture Sensitive
BRN 1761982
Stability:Stable. Flammable. Moisture-sensitive.
InChIKeyDCUFMVPCXCSVNP-UHFFFAOYSA-N
LogP1.23
CAS DataBase Reference760-93-0(CAS DataBase Reference)
NIST Chemistry ReferenceMethacrylic anhydride(760-93-0)
EPA Substance Registry SystemMethacrylic anhydride (760-93-0)
Safety Information
Hazard Codes Xn
Risk Statements 20-37/38-41
Safety Statements 26-39
RIDADR UN 3265 8/PG 2
WGK Germany 1
RTECS OZ5700000
10-21
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29161900
Hazardous Substances Data760-93-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
2-Methyl-2-Propenoic acid anhydride English
SigmaAldrich English
ALFA English
Methacrylic anhydride Usage And Synthesis
Chemical Propertiesliquid
UsesMethacrylic anhydride is a reactive monomer used for the preparation of different type of monomers under mild reaction conditions. It finds applications in light-curing coatings, cross-linked materials like synthetic resin. It acts as an intermediate for the preparation of fibers and resins.
General DescriptionLiquid.
Air & Water ReactionsReacts exothermically with water to form methacrylic acid.
Reactivity ProfileMethacrylic anhydride reacts exothermically with water. The reactions are sometimes slow, but can become violent when local heating accelerates their rate. Acids accelerate the reaction with water. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases.
Fire Hazard(Non-Specific -- Methacrylic Acid) Methacrylic anhydride may burn but may not ignite readily. Flammable/ poisonous gases may accumulate in tanks and hopper cars. Some of these materials may ignite combustibles (wood, paper, oil, etc.).
Purification MethodsDistil the anhydride at 2mm pressure, immediately before use, in the presence of hydroquinone. [Beilstein 2 IV 1537.]

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