Product

DIETHYL BENZYLPHOSPHONATE

CAS No.：1080-32-6

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DIETHYL BENZYLPHOSPHONATE Basic information

Product Name:	DIETHYL BENZYLPHOSPHONATE
Synonyms:	(phenylmethyl)-phosphonicacidiethylester;benzyl-phosphonicacidiethylester;Benzylphosphonsαurediethylester;Diethoxyphosphonomethylbenzene;Diethyl phosphonate, benzyl-;DIETHYL BENZOPHOSPHONATE;Phenylmethanephosphonic acid diethyl ester;Diethylbenzylphosphonate, 99 %
CAS:	1080-32-6
MF:	C11H17O3P
MW:	228.22
EINECS:	214-097-4
Product Categories:	Horner-Emmons Reaction;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:	1080-32-6.mol

DIETHYL BENZYLPHOSPHONATE Chemical Properties

Boiling point	106-108 °C1 mm Hg(lit.)
density	1.095 g/mL at 25 °C(lit.)
refractive index	n20/D 1.497(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
form	Liquid
Specific Gravity	1.10
color	Clear colorless to slightly yellow
Water Solubility	Insoluble in water.
BRN	2580931
CAS DataBase Reference	1080-32-6(CAS DataBase Reference)
EPA Substance Registry System	Phosphonic acid, (phenylmethyl)-, diethyl ester (1080-32-6)

Safety Information

Risk Statements	36/38-36/37/38
Safety Statements	24/25-37-26
WGK Germany	3
RTECS	SZ6600000
TSCA	Yes
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

DIETHYL BENZYLPHOSPHONATE Usage And Synthesis

Chemical Properties	CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
Uses	Reactant for synthesis of: ? 3,5-dihydroxy-4-isopropylstilbene for treatment of skin disorders ? Natural cytotoxic marine products of polyketide origin via intramolecular Diels-Alder reactions ? Stilbenes via on-column oxidation of vicinal diols and Horn
Uses	Diethyl benzylphosphonate is used as a reactant for synthesis of 3,5-dihydroxy-4-isopropylstilbene for treatment of skin disorders and natural cytotoxic marine products of polyketide origin via intramolecular Diels-Alder reactions. It is also used as reactant for cyclization of aryl ethers, amines and amides & for investigating the effects of functional groups on the performance of clue organic LEDs.
Uses	Reactant for synthesis of: 3,5-dihydroxy-4-isopropylstilbene for treatment of skin disorders Natural cytotoxic marine products of polyketide origin via intramolecular Diels-Alder reactions Stilbenes via on-column oxidation of vicinal diols and Horner-Emmons reactions Inhibitors of teh Wnt pathway for colon cancer repression using Wadsworth-Emmons reactions Antimalarial drug analogs against P. falciparum Reactant for: Cyclization of aryl ethers, amines, and amides Investigating the effects of functional groups on the performance of clue organic LEDs
Synthesis Reference(s)	Tetrahedron Letters, 29, p. 1513, 1988 DOI: 10.1016/S0040-4039(00)80339-1Synthesis, p. 222, 1981 DOI: 10.1055/s-1981-29393

DIETHYL BENZYLPHOSPHONATE Preparation Products And Raw materials

Preparation Products

2-CHLOROPHENETOLE

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