4-Chlorothiophenol

4-Chlorothiophenol
  • CAS No.:106-54-7
Other grades of this product :
4-Chlorothiophenol Basic information
Product Name:4-Chlorothiophenol
Synonyms:4-Chlorothiophenol/4-Chlorobenzenethiol;4-Cyano-Acetophonene/4-CA;4-Chloro;4-Chlorothiophenol 99%;4-chlorthiophenol;PARA-CHLOROTHIOPHENOL;BENZENETHIOL,PARA-CHLORO-;4-CHLOROTHIOPENOL
CAS:106-54-7
MF:C6H5ClS
MW:144.62
EINECS:203-408-9
Product Categories:Phenol&Thiophenol&Mercaptan;Phenoles and thiophenoles;Aromatic Phenols
Mol File:106-54-7.mol
4-Chlorothiophenol Chemical Properties
Melting point 49-51 °C(lit.)
Boiling point 205-207 °C(lit.)
density 1.1911
refractive index 1.5480
Fp >230 °F
storage temp. 2-8°C
solubility methanol: soluble
pkapK1:5.9 (25°C)
form Crystalline Solid
color White to almost white
Water Solubility insoluble
Sensitive Stench/Lachrymatory
BRN 605971
InChIKeyVZXOZSQDJJNBRC-UHFFFAOYSA-N
CAS DataBase Reference106-54-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenethiol, 4-chloro-(106-54-7)
EPA Substance Registry SystemBenzenethiol, 4-chloro- (106-54-7)
Safety Information
Hazard Codes C
Risk Statements 22-34-36/37-20/21/22
Safety Statements 26-36/37/39-45-27
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS DC1050000
9-13-23
Hazard Note Corrosive/Lachrymatory/Stench
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29309090
MSDS Information
ProviderLanguage
4-Chlorothiophenol English
ACROS English
SigmaAldrich English
ALFA English
4-Chlorothiophenol Usage And Synthesis
Chemical Propertieswhite to almost white crystalline solid
UsesOil additives, agricultural chemicals, plasticizers, rubber chemical, dyes, wetting agents, and stabilizers.
Uses4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.
Synthesis Reference(s)The Journal of Organic Chemistry, 27, p. 4455, 1962 DOI: 10.1021/jo01059a081Synthetic Communications, 18, p. 575, 1988 DOI: 10.1080/00397918808064014
General Description4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.
HazardToxic by ingestion.
Purification MethodsRecrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]

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