Product

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl

CAS No.：944451-28-9

Other grades of this product :

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Basic information

Product Name:	Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl
Synonyms:	Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl;(R)RuCl[(pcyMene)(SEGPHOS)]Cl;[RuCl(p-cymene)((R)-segphos(regR))]Cl;CHLORO[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE](P-CYMENE)RUTHENIUM(II) CHLORIDE,[RUCL(P-CYMENE)((R)-SEGPHOS;[RUCL(P-CYMENE)((R)-SEGPHOS)]CL;Reaxys ID: 11782476;-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((R)-segphos;Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos(R))]Cl
CAS:	944451-28-9
MF:	C48H40Cl2O4P2Ru
MW:	914.76
EINECS:
Product Categories:	Ru
Mol File:	944451-28-9.mol

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chemical Properties

Melting point	>100°C
storage temp.	2-8°C
Water Solubility	Insoluble in water
form	Powder
color	yellow
Sensitive	air sensitive

Safety Information

WGK Germany

MSDS Information

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Usage And Synthesis

Uses	Takasago Ligands and Complexes for Asymmetric Reactions
Reactions	1. Highly active highly enantioselective catalyst for hydrogenation of functionalized ketones. Slightly higher temperature is necessary to activate the cymene complexes. 2. Asymmetric hydrogenation of α-substituted-β-alkyl-β-ketoesters accompanied by dynamic kinetic resolution.

Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Preparation Products And Raw materials

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