TRIMETHYLENE SULFIDE

TRIMETHYLENE SULFIDE
  • CAS No.:287-27-4
Other grades of this product :
TRIMETHYLENE SULFIDE Basic information
Product Name:TRIMETHYLENE SULFIDE
Synonyms:THIACYCLOBUTAN;THIETANE;TRIMETHYLENE SULFIDE;TRIMETHYLENE SULPHIDE;1,3-Epithiopropan;Propane, 1,3-epithio-;propane,1,3-epithio-;Thiacyclobutane
CAS:287-27-4
MF:C3H6S
MW:74.14
EINECS:206-015-0
Product Categories:Building Blocks;Chemical Synthesis;Dithietanes;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds;Simple 4-Membered Ring Compounds
Mol File:287-27-4.mol
TRIMETHYLENE SULFIDE Chemical Properties
Melting point -73.24°C
Boiling point 94-94.5 °C (lit.)
density 1.028 g/mL at 25 °C (lit.)
refractive index n20/D 1.510(lit.)
Fp 27 °F
form liquid
Specific Gravity1.028
color Colorless to Almost colorless
BRN 102383
CAS DataBase Reference287-27-4(CAS DataBase Reference)
EPA Substance Registry SystemThietane (287-27-4)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-22
Safety Statements 16
RIDADR UN 1993 3/PG 2
WGK Germany 3
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIMETHYLENE SULFIDE Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
DefinitionChEBI: An organosulfur heterocyclic compound containing a saturated four membered ring with 3 carbon atom and 1 sulfur atom.
Purification MethodsPurify thietane by preparative gas chromatography on a dinonyl phthalate column. It has also been purified by drying over anhydrous K2CO3, and distilling through a 25cm glass helices-packed column (for 14g of thietane), then drying over CaSO4 before sealing it in a vacuum. [Haines et al. J Phys Chem 58 270 1954.] It is characterised as the dimethylsulfonium iodide m 97-98o [Bennett & Hock J Chem Soc 2496 1927]. The S-oxide has b 102o/25mm, n D 1.5075 [Tamres & Searles J Am Chem Soc 81 2100 1959]. [Beilstein 17 I 3, 17 II 12, 17 III/IV 14, 17/1 V 14.]
TRIMETHYLENE SULFIDE Preparation Products And Raw materials

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