(S)-4-Methyl-2,5-oxazolidonedione

(S)-4-Methyl-2,5-oxazolidonedione
  • CAS No.:2224-52-4
Other grades of this product :
(S)-4-Methyl-2,5-oxazolidonedione Basic information
Product Name:(S)-4-Methyl-2,5-oxazolidonedione
Synonyms:(S)-4-METHYL-OXAZOLIDINE-2,5-DIONE;(S)-4-METHYL-2,5-OXAZOLIDINEDIONE;(S)-4-Methyl-2,5-oxazolidonedione;H-ALA-NCA;Alanine, NCA;N-Carboxy-L-alanine anhydride;4-methyl-1,3-oxazolidine-2,5-dione;4-methyloxazolidine-2,5-quinone
CAS:2224-52-4
MF:C4H5NO3
MW:115.09
EINECS:218-750-4
Product Categories:AMINOACIDS DERIVATIVES
Mol File:2224-52-4.mol
(S)-4-Methyl-2,5-oxazolidonedione Chemical Properties
Melting point 92℃
alpha +5.13°(25/D,c=6.4,dioxane)
density 1.296
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility DMSO (Very Slightly, Heated)
form Solid
pka9.38±0.40(Predicted)
color White to Off-White
Safety Information
HS Code 2934999090
MSDS Information
(S)-4-Methyl-2,5-oxazolidonedione Usage And Synthesis
Uses(S)-4-Methyl-2,5-oxazolidonedione is a reagent used in the synthesis of poly(γ-benzyl-L-glutamate) and its block polypeptides with alanine, leucine and phenylalanine.
UsesN-Carboxyalanine Anhydride is a reagent used in the synthesis of poly(γ-benzyl-L-glutamate) and its block polypeptides with alanine, leucine and phenylalanine.
Synthesis Reference(s)The Journal of Organic Chemistry, 50, p. 2200, 1985 DOI: 10.1021/jo00212a042
(S)-4-Methyl-2,5-oxazolidonedione Preparation Products And Raw materials
Raw materialsDi-tert-butyl Tricarbonate-->N-(tert-Butoxycarbonyl)-L-alanine-->L-Alanine, N-(methoxycarbonyl)- (9CI)-->N-Carbobenzyloxy-L-alanine-->L-Alanine-->Triphosgene-->Chloroform-->Diphosgene
Preparation ProductsL-Alanyl-L-proline

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