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| Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Basic information | | Reactions |
| Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chemical Properties |
| Melting point | >100°C | | storage temp. | 2-8°C | | Water Solubility | Insoluble in water | | form | solid | | color | yellow to dark brown | | Sensitive | air sensitive |
| Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Usage And Synthesis |
| Reactions | 1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.
| | Uses | Takasago Ligands and Complexes for Asymmetric Reactions |
| Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Preparation Products And Raw materials |
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ruthenium(II)chloride](/img/228120-95-4.jpg "Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride")
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