Product

METHYL ALPHA-BROMOPHENYLACETATE

CAS No.：3042-81-7

Other grades of this product :

METHYL ALPHA-BROMOPHENYLACETATE Basic information

Product Name:	METHYL ALPHA-BROMOPHENYLACETATE
Synonyms:	-(1H-1,2,4-triazol-1-ylmethyl)-4-pyrimidineethanol-d3;-altropyranoside;Methyl alpha-bromobenzeneacetate;Methyl bromophenylacetate;Methyl2-bromo-2-phenylacetate;Methyla-bromo-a-phenylacetate;Methyla-bromobenzeneacetate;ALPHA-BROMOPHENYLACETIC ACID METHYL ESTER
CAS:	3042-81-7
MF:	C9H9BrO2
MW:	229.07
EINECS:	608-480-9
Product Categories:	Building Blocks;C8 to C9;Aromatic Phenylacetic Acids and Derivatives;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;C8 to C9;Carbonyl Compounds;Esters
Mol File:	3042-81-7.mol

METHYL ALPHA-BROMOPHENYLACETATE Chemical Properties

Boiling point	113 °C3 mm Hg(lit.)
density	1.46 g/mL at 20 °C(lit.)
refractive index	n20/D 1.554
Fp	>230 °F
storage temp.	2-8°C
form	clear liquid
color	Colorless to Light orange to Yellow
BRN	1102743
InChIKey	NHFBYYMNJUMVOT-UHFFFAOYSA-N

Safety Information

Hazard Codes	C
Risk Statements	36/37/38-34
Safety Statements	26-36/39-45-36/37/39
RIDADR	UN 3265 8/PG 2
WGK Germany	3
HazardClass	8
PackingGroup	II
HS Code	29163990

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

METHYL ALPHA-BROMOPHENYLACETATE Usage And Synthesis

Chemical Properties	Light yellow to yellow liquid
Uses	Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
Synthesis Reference(s)	Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6
General Description	Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

METHYL ALPHA-BROMOPHENYLACETATE Preparation Products And Raw materials

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