(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

CAS No.：138517-61-0

Other grades of this product :

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information

Reaction

Product Name:	(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:	(1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl;Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide];TROST LIGAND;(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1R,2R)-(+)-1,2-TROST LIGAND;"N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand"
CAS:	138517-61-0
MF:	C44H40N2O2P2
MW:	690.75
EINECS:
Product Categories:	Chiral Nitrogen;DACH&Trost Series
Mol File:	138517-61-0.mol

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties

Melting point	134-136°C
alpha	+130° (c 1.0, methanol)
Boiling point	817.0±65.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
pka	13.35±0.40(Predicted)
color	white to off-white
optical activity	[α]20/D +131°, c = 1 in methanol

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

MSDS Information

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis

Reaction	The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.
Uses	Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

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