| 2-Methylindoline Basic information |
| Product Name: | 2-Methylindoline |
| Synonyms: | 1H-Indole, 2,3-dihydro-2-methyl-;1H-Indole,2,3-dihydro-2-methyl-;2,3-dihydro-2-methyl-1h-indol;2,3-Dihydro-2-methyl-1H-indole;2-Methyl-2,3-dihydroindole;2-methyl-indolin;alpha-Methyldihydroindole;Dihydroindole, 2-methyl- |
| CAS: | 6872-06-6 |
| MF: | C9H11N |
| MW: | 133.19 |
| EINECS: | 229-971-0 |
| Product Categories: | Building Blocks;Heterocyclic Building Blocks;pharmacetical;Indoline & Oxindole;Heterocyclic Compounds;Indoles;Indoles and derivatives;Heterocycle-Indole series;intermediates |
| Mol File: | 6872-06-6.mol |
| 2-Methylindoline Chemical Properties |
| Melting point | -51 °C |
| Boiling point | 228-229 °C (lit.) |
| density | 1.023 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 200 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Chloroform, Methanol |
| form | Liquid |
| pka | 5.26±0.40(Predicted) |
| Specific Gravity | 1.02 |
| color | Clear yellow to brown |
| Water Solubility | negligible |
| CAS DataBase Reference | 6872-06-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 2-Methylindoline(6872-06-6) |
| EPA Substance Registry System | 1H-Indole, 2,3-dihydro-2-methyl- (6872-06-6) |
| Safety Information |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-52/53-22 |
| Safety Statements | 26-36/37/39-60-57 |
| WGK Germany | 3 |
| RTECS | NM1926350 |
| Hazard Note | Irritant |
| HS Code | 29349990 |
| MSDS Information |
| Provider | Language |
|---|---|
| 2-Methylindoline | English |
| ACROS | English |
| SigmaAldrich | English |
| 2-Methylindoline Usage And Synthesis |
| Chemical Properties | CLEAR YELLOW TO BROWN LIQUID |
| Uses | 2-Methylindoline is an intermediate in the production of various indole derivatives |
| Uses | Reactant for preparation of:
|
| Synthesis Reference(s) | Journal of the American Chemical Society, 111, p. 4108, 1989 DOI: 10.1021/ja00193a056Chemical and Pharmaceutical Bulletin, 26, p. 108, 1978 DOI: 10.1248/cpb.26.108 |
| 2-Methylindoline Preparation Products And Raw materials |
| Raw materials | 2-Methylindole-->Benzenamine, 2-(2-propyn-1-yl)--->Benzenamine, 2-(2-propenyl)--->N-ALLYLANILINE-->1-(2-bromophenyl)propan-2-amine |
| Preparation Products | Basic Yellow 21-->1H-Indole, 1-ethyl-2,3-dihydro-2-methyl--->5-BROMO-2-METHYLINDOLE |
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