4-Acetylphenylboronic acid

4-Acetylphenylboronic acid
  • CAS No.:149104-90-5
Other grades of this product :
4-Acetylphenylboronic acid Basic information
Product Name:4-Acetylphenylboronic acid
Synonyms:RARECHEM AH PB 0162;P-ACETYLPHENYLBORONIC ACID;TIMTEC-BB SBB000146;4-ACETYLPHENYLBORONIC ACID;4-ACETYLBENZENEBORONIC ACID;ACETOPHENONE-4-BORONIC ACID;AKOS BRN-0001;Boronic acid, (4-acetylphenyl)- (9CI)
CAS:149104-90-5
MF:C8H9BO3
MW:163.97
EINECS:629-086-3
Product Categories:Boronate Ester;Potassium Trifluoroborate;B (Classes of Boron Compounds);Boronic Acids;Boronic Acids;Boronic Acids and Derivatives;ACETYLGROUP;blocks;BoronicAcids;Boronic Acid series;Boronic Acid;Acetyl;Aryl;Organoborons;bc0001
Mol File:149104-90-5.mol
4-Acetylphenylboronic acid Chemical Properties
Melting point 240-244 °C(lit.)
Boiling point 354.2±44.0 °C(Predicted)
density 1.19±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Crystalline Powder
pka7.58±0.10(Predicted)
color Pale yellow to yellow
Water Solubility 25 g/L
BRN 7869162
CAS DataBase Reference149104-90-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
Hazard Note Irritant/Keep Cold
HazardClass IRRITANT
HS Code 29310095
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-Acetylphenylboronic acid Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powder
Usessuzuki reaction
UsesReactant involved in:
  • Palladium-catalyzed decarboxylative coupling
  • Copper-catalyzed hydroxylation
  • Palladium-catalyzed Suzuki-Miyaura cross-coupling
  • Cross-coupling with α-bromocarbonyl compounds
  • Oxidation catalyzed by Baeyer-Villiger monooxygenases
  • 1,5-substitution reactions
Uses4-Acetylphenylboronic acid4-Acetylphenylboronic Acid is used in several metal catalyzed cross-coupling reaction studies.
General Description4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.

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