(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
  • CAS No.:1019840-96-0
Other grades of this product :
(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Basic information
Reaction
Product Name:(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
Synonyms:(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin;(3aR,8aR)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e][1,32]dioxaphosphepin;1,3-Dioxolo[4,5-e][1,3,2]dioxaphosphepin, 4,4,8,8-tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-, (3aR,8aR)-
CAS:1019840-96-0
MF:C45H49O4P
MW:684.84
EINECS:
Product Categories:Chiral Phosphine;TADDOL Phos
Mol File:1019840-96-0.mol
(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Chemical Properties
Melting point 116-130 °C (decomp)
Boiling point 717.8±60.0 °C(Predicted)
form solid
color off-white
Safety Information
MSDS Information
(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Usage And Synthesis
Reaction
  1. Chiral ligand used in the nickel-catalyzed, enantioselective, conjugate allylation of activated enones.
  2. Chiral ligand used in the palladium-catalyzed, enantioselective diboration of terminal alkenes.
  3. Chiral ligand used in the palladium-catalyzed, asymmetric, 1,4-dihydroxylation of 1,3-dienes via catalytic enantioselective diboration.
  4. Chiral ligand used in the palladium-catalyzed diboration of N-silyated imines. 
(3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Preparation Products And Raw materials

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