Other grades of this product :
| (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Basic information | | Reaction |
| Product Name: | (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin | | Synonyms: | (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin;(3aR,8aR)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e][1,32]dioxaphosphepin;1,3-Dioxolo[4,5-e][1,3,2]dioxaphosphepin, 4,4,8,8-tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-, (3aR,8aR)- | | CAS: | 1019840-96-0 | | MF: | C45H49O4P | | MW: | 684.84 | | EINECS: | | Product Categories: | Chiral Phosphine;TADDOL Phos | | Mol File: | 1019840-96-0.mol |
| (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Chemical Properties |
| Melting point | 116-130 °C (decomp) | | Boiling point | 717.8±60.0 °C(Predicted) | | form | solid | | color | off-white |
| (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Usage And Synthesis |
| Reaction |
- Chiral ligand used in the nickel-catalyzed, enantioselective, conjugate allylation of activated enones.
- Chiral ligand used in the palladium-catalyzed, enantioselective diboration of terminal alkenes.
- Chiral ligand used in the palladium-catalyzed, asymmetric, 1,4-dihydroxylation of 1,3-dienes via catalytic enantioselective diboration.
- Chiral ligand used in the palladium-catalyzed diboration of N-silyated imines.
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| (3aR,8aR)-(-)-4,4,8,8-Tetrakis (3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Preparation Products And Raw materials |
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