| 3-BROMOCHLOROBENZENE Basic information |
| Product Name: | 3-BROMOCHLOROBENZENE |
| Synonyms: | 1-bromo-3-chloro-benzen;1-Chloro-3-bromobenzene;3-Bromo-1-chlorobenzene;1-BROMO-3-CHLOROBENZENE;3-BROMOCHLOROBENZENE;M-CHLOROBROMOBENZENE;M-BROMOCHLOROBENZENE;3-BROMOCHLOROBENZENE 99% |
| CAS: | 108-37-2 |
| MF: | C6H4BrCl |
| MW: | 191.45 |
| EINECS: | 203-575-8 |
| Product Categories: | alkyl bromide| alkyl chloride;Building Blocks;Bromine Compounds;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Aromatic Halides (substituted);Chlorine Compounds;Aryl;C6;Halogenated Hydrocarbons |
| Mol File: | 108-37-2.mol |
| 3-BROMOCHLOROBENZENE Chemical Properties |
| Melting point | -21.5 °C |
| Boiling point | 196 °C(lit.) |
| density | 1.63 g/mL at 25 °C(lit.) |
| refractive index | n |
| Fp | 177 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | Liquid |
| Specific Gravity | 1.630 |
| color | Clear colorless to light yellow |
| Water Solubility | Insoluble |
| BRN | 1446353 |
| CAS DataBase Reference | 108-37-2(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-Chlorobromobenzene(108-37-2) |
| EPA Substance Registry System | Benzene, 1-bromo-3-chloro- (108-37-2) |
| Safety Information |
| Hazard Codes | Xi,Xn |
| Risk Statements | 36/37/38-20/22 |
| Safety Statements | 26-36-37/39 |
| WGK Germany | 3 |
| RTECS | CY9005000 |
| Hazard Note | Irritant |
| TSCA | Yes |
| HS Code | 29039990 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 3-BROMOCHLOROBENZENE Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS TO LIGHT YELLOW LIQUID |
| Uses | 1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. |
| Synthesis Reference(s) | The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031 |
| General Description | 1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. |
| 3-BROMOCHLOROBENZENE Preparation Products And Raw materials |
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