(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
  • CAS No.:15186-48-8
Other grades of this product :
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Basic information
Product Name:(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde
Synonyms:1,3-DIOXOLANE-4-CARBOXALDEHYDE, 2,2-DIMETHYL-, (R)-;(R)-2,2-DIMETHYL-[1,3]DIOXOLANE-4-CARBALDEHYDE;(R)-(+)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXALDEHYDE;(R)-2,3-ISOPROPYLIDENE GLYCERALDEHYDE;2,3-O-ISOPROPYLIDENE-D-GLYCERALDEHYDE;2,3-O-(R)-ISOPROPYLIDENE-L-GLYCERALDEHYDE;(4R)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBALDEHYDE;D-(R)-GLYCERALDEHYDE ACETONIDE
CAS:15186-48-8
MF:C6H10O3
MW:130.14
EINECS:676-289-8
Product Categories:Asymmetric Synthesis;Building Blocks;C1 to C6;Carbonyl Compounds;Chemical Synthesis;Chiral Building Blocks;pharmacetical;chiral;Chiral Reagents;Aldehydes;Chiral Building Blocks;Organic Building Blocks;Heterocyclic Building Blocks;Organic Building Blocks;API intermediates;Heterocycles
Mol File:15186-48-8.mol
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Chemical Properties
Boiling point 139 °C (lit.)
alpha 53.8 º (c=2, CHCl3)
density 1.045 g/mL at 25 °C (lit.)
refractive index n20/D 1.454(lit.)
Fp 143 °F
storage temp. -20°C
solubility Difficult to mix.
form Liquid
color Colorless to Pale Yellow
optical activity[α]22/D +53.8°, c = 2 in chloroform
CAS DataBase Reference15186-48-8(CAS DataBase Reference)
NIST Chemistry ReferenceAcetone D-glyceraldehyde(15186-48-8)
Safety Information
WGK Germany 3
HazardClass 6.1
HS Code 29329990
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Usage And Synthesis
Chemical PropertiesColorless Transparent Liquid
Uses(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde is a reactant involved in organic reactions including:• ;Henry condensation reactions1• ;Synthesis of highly functionalized chiral aziridines2• ;Olefination of aldehydes3• ;C-H oxidations4• ;Aldol-type condensations5• ;Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents6• ;Hosomi-Sakurai reactions7
Uses(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde_x000D__x000D_Discontinued, Unstable (cas# 15186-48-8) is a compound useful in organic synthesis.
UsesReactant involved in organic reactions including:
  • Henry condensation reactions
  • Synthesis of highly functionalized chiral aziridines
  • Olefination of aldehydes
  • C-H oxidations
  • Aldol-type condensations
  • Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents
  • Hosomi-Sakurai reactions
(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde Preparation Products And Raw materials
Preparation Products(S)-(+)-(2,2-DIMETHYL-[1,3]-DIOXOLAN-4-YL)-METHYLAMINE-->D-Glyceraldehyde

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