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| DIETHYL (CHLOROMETHYL)PHOSPHONATE Basic information |
| DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties |
| Boiling point | 109-110 °C10 mm Hg(lit.) | | density | 1.2 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.437(lit.) | | Fp | 188 °F | | storage temp. | 2-8°C | | form | Liquid | | Specific Gravity | 1.2 | | color | Clear colorless to light yellow | | BRN | 1363361 | | EPA Substance Registry System | Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | Hazard Note | Irritant | | HS Code | 29319090 |
| DIETHYL (CHLOROMETHYL)PHOSPHONATE Usage And Synthesis |
| Chemical Properties | Clear colorless to light yellow liquid | | Uses | Reactant involved in:- Subsequent alkylation after nucleophilic substitution
- One-pot alkylation-boration of α-haloalkylphosphonates
- Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
- Phosphorylation leading to P-containing cyclopropanes
- Wadsworth-Emmons reactions
- Ring expansion of zircnacycles via carbenoid insertion
| | Synthesis Reference(s) | Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1 |
| DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials |
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