| 3-(Trifluoromethoxy)bromobenzene Basic information |
| Product Name: | 3-(Trifluoromethoxy)bromobenzene |
| Synonyms: | 3-Bromophenyl trifluoromethyl ether, 3-Bromo-alpha,alpha,alpha-trifluoroanisole;3-(trifluoromrthoxy)bromobenzene;Inter-bromo-trifluoromethoxy benzene;Anisole, m-bromo-alphaalphaalpha-trifluoro-;BUTTPARK 91\57-27;M-BROMO(TRIFLUOROMETHOXY)BENZENE;3-(TRIFLUOROMETHOXY)BROMOBENZENE;3-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE |
| CAS: | 2252-44-0 |
| MF: | C7H4BrF3O |
| MW: | 241.01 |
| EINECS: | |
| Product Categories: | Fluorobenzene;Trifluoroanisole series;Halides;Aromatic Ethers;Phenyls & Phenyl-Het;Miscellaneous;Phenyls & Phenyl-Het;Ethers;Organic Building Blocks;Oxygen Compounds;alkyl bromide |
| Mol File: | 2252-44-0.mol |
| 3-(Trifluoromethoxy)bromobenzene Chemical Properties |
| Boiling point | 156-158 °C |
| density | 1.62 g/mL at 25 °C(lit.) |
| refractive index | n |
| Fp | 145 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 1.64 |
| BRN | 1945938 |
| CAS DataBase Reference | 2252-44-0(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-(Trifluoromethoxy)bromobenzene(2252-44-0) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 37/39-26-24/25 |
| WGK Germany | 3 |
| HazardClass | IRRITANT |
| HS Code | 29049090 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| 3-(Trifluoromethoxy)bromobenzene Usage And Synthesis |
| Chemical Properties | Clear very faintly yellow liquid |
| Uses | 1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl]. |
| General Description | 1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes. |
| 3-(Trifluoromethoxy)bromobenzene Preparation Products And Raw materials |
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