3-Methyl-2-butenal

3-Methyl-2-butenal
  • CAS No.:107-86-8
Other grades of this product :
3-Methyl-2-butenal Basic information
Product Name:3-Methyl-2-butenal
Synonyms:2-Butenal, 3-methyl-;3-methyl-2-butena;3-Methyl-2-butenal, 97% 5ML;3,3-Dimethylacrolein 3-Methylcrotonaldehyde Senecialdehyde;3-Methylcrotonaldehyde 97%;3-Methyl-2-butenal, 96%, 96%;3-methyl-2-butenal (prenal);3-methyl-but-2-enal
CAS:107-86-8
MF:C5H8O
MW:84.12
EINECS:203-527-6
Product Categories:
Mol File:107-86-8.mol
3-Methyl-2-butenal Chemical Properties
Melting point -20°C
Boiling point 133-135 °C (lit.)
density 0.878 g/mL at 20 °C 0.872 g/mL at 25 °C (lit.)
vapor pressure 7 mm Hg ( 20 °C)
refractive index n20/D 1.462(lit.)
FEMA 3646 | 3-METHYL-2-BUTENAL
Fp 93 °F
storage temp. 2-8°C
solubility soluble
form Liquid
color Clear colorless to light yellow
Water Solubility soluble
Sensitive Air Sensitive
Merck 14,8448
JECFA Number1202
BRN 1734740
LogP0.53 at 25℃
CAS DataBase Reference107-86-8(CAS DataBase Reference)
NIST Chemistry Reference3-methyl-2-butenal(107-86-8)
EPA Substance Registry System2-Butenal, 3-methyl- (107-86-8)
Safety Information
Hazard Codes Xn,Xi,C
Risk Statements 10-22-37/38-41-43-36/37/38-34-20/22-20/21/22
Safety Statements 26-36-37/39-16-45-36/37/39
RIDADR UN 1989 3/PG 3
WGK Germany 2
9-13-23
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29121900
MSDS Information
ProviderLanguage
Prenal English
ACROS English
SigmaAldrich English
ALFA English
3-Methyl-2-butenal Usage And Synthesis
Description3-Methyl-2-butenal has an almond odor.
Chemical Properties3-Methyl-2-butenal has an almond odor
Chemical Propertiesclear colorless to light yellow liquid
Uses3-Methyl-2-butenal is used in small quantities as food flavor in alcoholic beverages, chewing gums, confection frosting, frozen dairy, fruit ice, gelatin pudding, hard and soft candy and jam jelly. Used in daily flavor, and cosmetic flavor in perfumes. A starting material for the synthesis of vitamin A.
DefinitionChEBI: An enal consisting of but-2-ene with a methyl substituent at position 3 and an oxo group at position 1.
Taste threshold valuesTaste characteristics at 25 ppm: sweet, fruity and green with a nutty and cherry background.
General Description3-Methylcrotonaldehyde is an α, β-unsaturated aldehyde. Electrochemical dimerization of 3-methylcrotonaldehyde was reported. The hydrogenation of 3-methylcrotonaldehyde over Ru, Pt and Rh was investigated.
Purification MethodsThis flammable oil oxidises readily and should be fractionated under N2. It should be stored under N2 and/or vacuum. The UV has max at 235.5nm. The semicarbazone has m 221-222o (from MeOH) and the 2,4-dinitrophenylhydrazone has m 184-185o (from MeOH). [Forbes & Skilton J Org Chem 24 436 1959, Beilstein 1 III 2990, 1 IV 3464.]

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