| 3-Chlorostyrene Basic information |
| Preparation |
| Product Name: | 3-Chlorostyrene |
| Synonyms: | styrene,m-chloro-;Chlorostyrenestabilisedwithtertbutylcatechol;3-Chlorostyrene, stabilized, 98%;3-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL;3-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol;3-CHLOROSTYRENE, 98%, STAB. WITH 0.1% 4-TERT-BUTYLCATECHOL;3-Chlorostyrene (stabilized with TBC);3-Chlorovinylbenzene |
| CAS: | 2039-85-2 |
| MF: | C8H7Cl |
| MW: | 138.59 |
| EINECS: | 218-024-7 |
| Product Categories: | Monomers;Polymer Science;Styrenes;Styrene and Functionalized Styrene Monomers |
| Mol File: | 2039-85-2.mol |
| 3-Chlorostyrene Chemical Properties |
| Melting point | -23.4°C (estimate) |
| Boiling point | 60-62 °C (6 mmHg) |
| density | 1.09 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 145 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Water Solubility | Not miscible or difficult to mix in water. Soluble in ether, and ethanol |
| BRN | 2038489 |
| CAS DataBase Reference | 2039-85-2(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-ClC6H4CH=CH2(2039-85-2) |
| EPA Substance Registry System | m-Chlorostyrene (2039-85-2) |
| Safety Information |
| Hazard Codes | Xn,Xi |
| Risk Statements | 20/22-36/37/38 |
| Safety Statements | 36-37/39-26-24/25 |
| RIDADR | 1993 |
| WGK Germany | 3 |
| HazardClass | IRRITANT |
| PackingGroup | III |
| HS Code | 29039990 |
| Hazardous Substances Data | 2039-85-2(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| 3-Chlorostyrene | English |
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| 3-Chlorostyrene Usage And Synthesis |
| Preparation | 1-(m-Chlorophenyl)ethanol is reacted with potassium hydrogen sulfate in the presence of p-tert-butylcatechol to give m-chlorostyrene. |
| Chemical Properties | Clear colourless liquid |
| Uses | 3-Chlorostyrene has been identified as a potential candidate for an electron resist to be used in direct device fabrication. |
| Synthesis Reference(s) | Journal of the American Chemical Society, 70, p. 1180, 1948 DOI: 10.1021/ja01183a088Organic Syntheses, Coll. Vol. 3, p. 204, 1955 |
| Synthesis Reference(s) | Synthetic Communications, 11, p. 405, 1981 DOI: 10.1080/00397918108064307 |
| 3-Chlorostyrene Preparation Products And Raw materials |
| Raw materials | Potassium bisulfate-->4-tert-Butylcatechol-->1-(3-Chlorophenyl)-1-ethanol-->3-Chlorophenylacetylene |
| Preparation Products | 1-Chloro-3-ethylbenzene-->3-CHLOROPHENACYL BROMIDE-->2,3'-Dichloroacetophenone |
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