Terbutryn

Terbutryn
  • CAS No.:886-50-0
Other grades of this product :
Terbutryn Basic information
Product Name:Terbutryn
Synonyms:TERBUTREX;TERBUTRYN;TERBUTRYNE;TERNIT;SUNTER;n-(1,1-dimethylethyl)-n'-ethyl-6-(methylthio)-1,3,5-triazine-2,4-diamine;PREBANE;PREBANE(R)
CAS:886-50-0
MF:C10H19N5S
MW:241.36
EINECS:212-950-5
Product Categories:Pyridazines;Agro-Products;Amines;Bases & Related Reagents;Heterocycles;Isotope Labelled Compounds;HERBICIDE;TA - TEPesticides&Metabolites;Alpha sort;Herbicides;Pesticides&Metabolites;Q-ZAlphabetic;Nucleotides;Sulfur & Selenium Compounds;Triazines;Alphabetic
Mol File:886-50-0.mol
Terbutryn Chemical Properties
Melting point 104-105°C
Boiling point 154-160°C
density 1.45
refractive index 1.5500 (estimate)
Fp 2 °C
storage temp. APPROX 4°C
form Powder
pka4.03±0.10(Predicted)
color White
Water Solubility 0.0025 g/100 mL
BRN 611817
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference886-50-0(CAS DataBase Reference)
NIST Chemistry ReferenceTerbutryn(886-50-0)
EPA Substance Registry SystemTerbutryn (886-50-0)
Safety Information
Hazard Codes Xi,N,Xn,F
Risk Statements 36-50/53-20/21/22-11
Safety Statements 26-60-61-36/37-16
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS XY4725000
Hazardous Substances Data886-50-0(Hazardous Substances Data)
ToxicityLC50 (96-hour) for rainbow trout 3 mg/L, bluegill sun?sh 4 mg/L, carp 4 mg/L and perch 4 mg/L (Hartley and Kidd, 1987); acute oral LD50 for rats 2,500 mg/kg (Hartley and Kidd, 1987), 2,045 mg/kg (RTECS, 1985).
MSDS Information
Terbutryn Usage And Synthesis
DescriptionTerbutin is a systemic and conductive herbicide, which can be used for pre-emergence and post-emergence weeding, and the effective period in the soil is 3-10 weeks. It is mainly used in winter wheat, barley, sorghum, sunflower, potatoes, peas, soybeans, peanuts and other crop fields to control perennial ryegrass, ryegrass and autumn germinating chickweed, marigolds, poppies, kangaroo, crabgrass, foxtail Wait.
Chemical Propertiessolid
UsesA triazine herbicide.
UsesA labelled triazine herbicide.
UsesSelective herbicide for control of annual broad-leaved and grass weeds in wheat.
DefinitionChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by a tert-butylamino and an ethylamino group at positions 2 and 4 respectively.
SynthesisCyanuric chloride reacts with ter-butylamine to generate 2,4-dichloro-6-tert-butylamino-1,3,5-triazine; then reacts with ethylamine to generate 2-chloro-4-ethylamino-6-tertiary Butylamino-1,3,5-triazine, and finally reacts with methyl mercaptan to generate Terbutryn.
Environmental FatePlant. In plants, the methylthio group is oxidized to hydroxy derivatives and by dealkylation of the side chains. Residual activity in soil is limited to approximately 3–10 weeks (Hartley and Kidd, 1987).
Terbutryn Preparation Products And Raw materials
Raw materialsCyanuric chloride-->tert-Butylamine-->METHYL MERCAPTAN-->1,3,5-Triazine-->Terbutylazine

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