4-Aminodiphenylamine

4-Aminodiphenylamine
  • CAS No.:101-54-2
Other grades of this product :
4-Aminodiphenylamine Basic information
Product Name:4-Aminodiphenylamine
Synonyms:4-(Phenylamino)aniline;4-amino-diphenylamin;VARIAMINE BLUE RT;Variamine Blue RT Base;Fast Blue R Salt;fastbluersalt;FastblueRTbase;Luxan Black R
CAS:101-54-2
MF:C12H12N2
MW:184.24
EINECS:202-951-9
Product Categories:Indazoles;Intermediates of Dyes and Pigments;101-54-2
Mol File:101-54-2.mol
4-Aminodiphenylamine Chemical Properties
Melting point 69 °C
Boiling point 354 °C
density 1.09
vapor pressure 1 hPa
refractive index 1.6266 (estimate)
Fp 193°C
storage temp. Store below +30°C.
solubility ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
pka5.20±0.10(Predicted)
form Liquid
Colour Index 37240
color Clear
PH8.9 (0.5g/l, H2O, 20℃)
Water Solubility Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
BRN 908935
Stability:Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
LogP1.82 at 20℃ and pH7
Dissociation constant5.45-5.47 at 20℃
CAS DataBase Reference101-54-2(CAS DataBase Reference)
NIST Chemistry Reference1,4-Benzenediamine, N-phenyl-(101-54-2)
EPA Substance Registry Systemp-Aminodiphenylamine (101-54-2)
Safety Information
Hazard Codes Xn,Xi,N
Risk Statements 22-36-43-42/43-36/37/38-20/22-50/53
Safety Statements 26-36-45-36/37/39-61-60-36/37
RIDADR UN3077
WGK Germany 3
RTECS ST3150000
8
Autoignition Temperature>500 °C
Hazard Note Irritant
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29215990
Hazardous Substances Data101-54-2(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg
MSDS Information
ProviderLanguage
4-Aminodiphenylamine English
SigmaAldrich English
ACROS English
ALFA English
4-Aminodiphenylamine Usage And Synthesis
Descriptionp-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.
Chemical PropertiesDark grey flake
UsesDye intermediate, pharmaceuticals, photographic chemicals.
Uses4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.
Usesp-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye.
DefinitionChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.
General DescriptionOdorless purple-black solid or flake or dark purple chips.
Air & Water ReactionsInsoluble in water.
Reactivity Profile4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.
Fire Hazard4-Aminodiphenylamine is combustible.
Contact allergensThis substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.
Purification MethodsIt crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]

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