(Pentamethylcyclopentadienyl)iridium(III) chloride dimer

CAS No.：12354-84-6

Other grades of this product :

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Basic information

Reaction

Product Name:	(Pentamethylcyclopentadienyl)iridium(III) chloride dimer
Synonyms:	(PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer, 99% 250MG;PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer,98% (CpIrCl2)2;(PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III) CHLORIDE DIMER;Dichloro(pentaMethylcyclopentadienyl)iridiuM(III)diMMer;Pentamethylcyclopentadienyliridium(Ⅲ) chloride dimer;PentaMethylcyclopentadienyl)iridiuM(III) chloride diMer,(CpIrCl2)2;PentaMethylcyclopentadienyliridiuM(Ⅲ) chloride diMer, 48% Ir, Product of UMicore;PentaMethylcyclopentadienyliridiuM(III) chloride,diMer 96%
CAS:	12354-84-6
MF:	C20H30Cl4Ir210*
MW:	796.7
EINECS:
Product Categories:	Ir;organometallic complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Ir (Iridium) Compounds;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Iridium
Mol File:	12354-84-6.mol

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Chemical Properties

Melting point	245 °C (decomp)(Solv: chloroform (67-66-3); hexane (110-54-3))
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	orange
CAS DataBase Reference	12354-84-6

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38-R36/37/38
Safety Statements	37/39-26-S37/39-S26-24/25
WGK Germany	3
TSCA	No
HS Code	28439000

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Usage And Synthesis

Reaction	Iridium-catalyzed C-3 alkylation of oxindole with alcohols. Precursor to N-heterocyclic carbene catalyst effective for hydrogenation and alkylation of amines and alcohols. Precursor to efficient phosphine free catalyst for enantioselective hydrogenation of quinoline derivatives. Catalyst for oxidative C–H activation. Precursor to an effective water oxidation catalyst.
Chemical Properties	orange fine crystalline powder
Uses	Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.
General Description	This product has been enhanced for catalytic efficiency.

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer Preparation Products And Raw materials

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