Hexadecafluoroheptane

Hexadecafluoroheptane
  • CAS No.:335-57-9
Other grades of this product :
Hexadecafluoroheptane Basic information
Product Name:Hexadecafluoroheptane
Synonyms:HEXADECAFLUOROHEPTANE;Perfluoroheptanes, mixture of isomers, 98%;Perfluoroheptane 97%;Hexadecafluoroheptane technical grade, 85%;PERFLUORO-N-HEPTANE;PERFLUOROHEPTANE;Perfluoroheptane (mixed isomers);PERFLUOROHEPTANE(S)
CAS:335-57-9
MF:C7F16
MW:388.05
EINECS:206-392-1
Product Categories:Fluorous Chemistry;Fluorous Solvents;Synthetic Organic Chemistry
Mol File:335-57-9.mol
Hexadecafluoroheptane Chemical Properties
Melting point -51.2°C
Boiling point 82-84 °C(lit.)
density 1.745 g/mL at 25 °C(lit.)
refractive index n20/D 1.3(lit.)
Fp 80-82°C
storage temp. Refrigerator, under inert atmosphere
solubility Chloroform, Methanol (Sparingly)
form A liquid
Specific Gravity1.72
color Colourless
BRN 1716335
InChIKeyLGUZHRODIJCVOC-UHFFFAOYSA-N
CAS DataBase Reference335-57-9(CAS DataBase Reference)
NIST Chemistry ReferenceHeptane, hexadecafluoro-(335-57-9)
EPA Substance Registry SystemPerfluoroheptane (335-57-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS MJ0875000
Hazard Note Irritant
TSCA Yes
HS Code 29033990
ToxicityLDLo ipr-mus: 4 g/kg CBCCT* 4,108,52
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Hexadecafluoroheptane Usage And Synthesis
Chemical PropertiesClear light yellow liquid
UsesHexadecafluoroheptane may be employed in solution-phase studies of perfluoropolyalkylene oligomers and in the preparation of fluorinated gel emulsions.
General DescriptionHexadecafluoroheptane is a common liquid perfluoro-n-alkane. It is reported as fluorinated solvent. Encapsulation of hexadecafluoroheptane (Perfluoroheptane) by a microencapsulation method based on a Pickering emulsion templated interfacial atom transfer radical polymerization (PETI-ATRP) has been reported. Aggregation of diblock semifluorinated in perfluoroheptane (fluorinated solvent) has been reported. Physical properties and commercial/industrial uses of hexadecafluoroheptane has been reported.
Safety ProfileLow toxicity by intraperitoneal route. Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes such as Fí.
Purification MethodsPurify it as for perfluorodimethylhexane. Other procedures include shaking with H2SO4, washing with water, drying with P2O5 for 48hours and fractionally distilling. Alternatively, it has been refluxed for 24hours with saturated acid KMnO4 (to oxidise and remove hydrocarbons), then neutralised, steam distilled, dried with P2O5, and passed slowly through a column of dry silica gel. It has been purified by fractional crystallisation using partial freezing. [Beilstein 1 IV 388.]
Hexadecafluoroheptane Preparation Products And Raw materials

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