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| (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Basic information |
| Product Name: | (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE | | Synonyms: | (4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Phenylpinacolborane;Pinacol phenylboronate;1,3,2-Dioxaborolane,4,4,5,5-tetraMethyl-2-phenyl-;(Pinacolboryl)benzene;Phenylboronic acid pinacol ester 97%;cyclic tetramethylethylene ester benzeneboronic acid;PHENYL-BORONIC ACID PINACOL ESTER | | CAS: | 24388-23-6 | | MF: | C12H17BO2 | | MW: | 204.07 | | EINECS: | | Product Categories: | | Mol File: | 24388-23-6.mol |
| (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Chemical Properties |
| Melting point | 27-31 °C(lit.) | | Boiling point | 130°C/20mmHg(lit.) | | density | 0.99±0.1 g/cm3(Predicted) | | Fp | 225 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | form | powder to lump | | color | White to Almost white | | InChIKey | KKLCYBZPQDOFQK-UHFFFAOYSA-N | | CAS DataBase Reference | 24388-23-6(CAS DataBase Reference) |
| Hazard Codes | Xn,Xi | | Risk Statements | 22-36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 | | Hazard Note | Irritant | | HS Code | 29319090 |
| (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Usage And Synthesis |
| Chemical Properties | White to light yellow crystal | | Uses | Phenylboronic acid pinacol ester can be used:- To prepare sulfinamide derivatives by reacting with diethylaminosulfur trifluoride (DAST) and potassium phenyltrifluoroborate.
- As a substrate in the study of Suzuki–Miyaura coupling of various aryl iodides over SiliaCat?Pd(0).
| | Uses | suzuki reaction | | Synthesis Reference(s) | The Journal of Organic Chemistry, 60, p. 7508, 1995 DOI: 10.1021/jo00128a024 | | General Description | Phenylboronic acid, pinacol ester, also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaura?reaction. |
| (4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE Preparation Products And Raw materials |
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