| Dibenzyl azodicarboxylate Basic information |
| Product Name: | Dibenzyl azodicarboxylate |
| Synonyms: | Dibenzy| azodicarbo×ylate;diazenedicarboxylicacid,bis(phenylmethyl)ester;Phenylmethyl N-(phenylmethoxycarbonylimino)carbamate;Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca. 1.7mol/L);Azobis(formic acid benzyl) ester;Azodiformic acid dibenzyl ester;Bis(benzyloxycarbonyl)diazene;Diazene-1,2-dicarboxylic acid dibenzyl ester |
| CAS: | 2449-05-0 |
| MF: | C16H14N2O4 |
| MW: | 298.29 |
| EINECS: | 219-508-0 |
| Product Categories: | Aromatic Esters;Azo/Diazo Compounds;Nitrogen Compounds;Organic Building Blocks |
| Mol File: | 2449-05-0.mol |
| Dibenzyl azodicarboxylate Chemical Properties |
| Melting point | 43-47 °C (lit.) |
| Boiling point | 439.72°C (rough estimate) |
| density | 1.2028 (rough estimate) |
| refractive index | 1.6240 (estimate) |
| Fp | >230 °F |
| storage temp. | 2-8°C |
| form | Crystalline Powder |
| color | Yellow to orange |
| Sensitive | Light Sensitive |
| BRN | 2298734 |
| InChIKey | IRJKSAIGIYODAN-ISLYRVAYSA-N |
| CAS DataBase Reference | 2449-05-0(CAS DataBase Reference) |
| EPA Substance Registry System | Diazenedicarboxylic acid, bis(phenylmethyl) ester (2449-05-0) |
| Safety Information |
| Hazard Codes | Xi,F |
| Risk Statements | 36/37/38-11 |
| Safety Statements | 26-37/39-16 |
| RIDADR | 3224 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 29270000 |
| MSDS Information |
| Provider | Language |
|---|---|
| Dibenzyl azodicarboxylate | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Dibenzyl azodicarboxylate Usage And Synthesis |
| Chemical Properties | yellow to orange crystalline powder |
| Uses | Dibenzyl azodicarboxylate is a reagent used in the synthesis of Minocycline-d6 (M344797). Minocycline-d6 is a labeled second generation tetracycline antibiotic. Antibacterial. |
| Uses | Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives. |
| General Description | Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides. |
| Dibenzyl azodicarboxylate Preparation Products And Raw materials |
| Raw materials | 1,2-DICARBOBENZYLOXYHYDRAZINE |
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