| EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Basic information |
| Product Name: | EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE |
| Synonyms: | TFMC-EU;TRIS(TRIFLUOROMETHYLHYDROXYMETHYLENE-D-CAMPHORATO)EUROPIUM(III);TRIS(3-TRIFLUOROACETYL-D-CAMPHORATO)EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III);TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO], EUROPIUM(III) DERIVATIVE;GDCL3:6H2O;EU(FACAM)3;Tris[3-(trifluoromethylhydroxymethylene)-D-camphorato], europium(III) derivative,95% |
| CAS: | 34830-11-0 |
| MF: | C36H42EuF9O6 |
| MW: | 893.68 |
| EINECS: | 252-232-9 |
| Product Categories: | Chiral Shift ReagentsStable Isotopes;Asymmetric Synthesis;Chiral Resolution Reagents;NMR - Buffers and Reagents;NMR Solvents and Reagents |
| Mol File: | 34830-11-0.mol |
| EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Chemical Properties |
| Melting point | 195-198 °C(lit.) |
| form | solid |
| optical activity | [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free) |
| Water Solubility | Soluble in chloroform. Insoluble in water. |
| Sensitive | Moisture Sensitive |
| CAS DataBase Reference | 34830-11-0 |
| EPA Substance Registry System | Europium, tris[1,7,7-trimethyl-3-(trifluoroacetyl-.kappa.O)bicyclo[2.2.1]heptan-2-onato-.kappa.O]- (34830-11-0) |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Usage And Synthesis |
| Chemical Properties | yellow to orange powder |
| Uses | Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride. Also reactant involved in synthesis of europium acetyl camphorate phosphine oxide complexes and reactions with 1,10-N,N?-phenanthroline dioxide derivatives. |
| EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE Preparation Products And Raw materials |
| Raw materials | Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Diethyl ether-->Hexane-->Sodium hydride-->Pentane-->DME-->Ethyl trifluoroacetate-->D-CAMPHOR-->EUROPIUM(III) CHLORIDE HEXAHYDRATE |
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