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| PHENYLSELENYL BROMIDE Basic information |
| PHENYLSELENYL BROMIDE Chemical Properties |
| Melting point | 58-62 °C (lit.) | | Boiling point | 107-108 °C/15 mmHg (lit.) | | Fp | 107-108°C/15mm | | storage temp. | 2-8°C | | solubility | Soluble in toluene, very faint turbidity. | | form | solid | | color | Orange to Brown to Dark purple | | Sensitive | Moisture Sensitive | | BRN | 2039772 | | Exposure limits | ACGIH: TWA 0.2 mg/m3NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 | | InChIKey | LCEFEIBEOBPPSJ-UHFFFAOYSA-N | | CAS DataBase Reference | 34837-55-3(CAS DataBase Reference) |
| PHENYLSELENYL BROMIDE Usage And Synthesis |
| Chemical Properties | dark brownish to black crystals | | Uses | Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione. | | Purification Methods | Distil it in a vacuum, recrystallise it from pet ether, CHCl3 (EtOH free), or Et2O (cooling mixture) to give dark red or orange crystals. These sublime at 25o/0.001mm [Behaghel et al. Chem Ber 65 815 1932, Pitteloud & Petrzilka Helv Chim Acta 62 1319 1979]. [Beilstein 6 III 1111.] HIGHLY TOXIC. |
| PHENYLSELENYL BROMIDE Preparation Products And Raw materials |
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