Ethyl 4-bromobenzoate

CAS No.：5798-75-4

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Ethyl 4-bromobenzoate Basic information

Product Name:	Ethyl 4-bromobenzoate
Synonyms:	ETHYL P-BROMOBENZOATE;ETHYL 4-BROMOBENZOATE;4-BROMOBENZOIC ACID ETHYL ESTER;RARECHEM AL BI 0075;4-bromo-benzoicaciethylester;Benzoic acid, p-bromo-, ethyl ester;p-(Ethoxycarbonyl)phenyl bromide;Ethyl 4-BroMobenzoate, 98.0%(GC)
CAS:	5798-75-4
MF:	C9H9BrO2
MW:	229.07
EINECS:	227-347-2
Product Categories:	Aromatic Esters;Acids & Esters;Bromine Compounds;C8 to C9;Carbonyl Compounds;Esters
Mol File:	5798-75-4.mol

Ethyl 4-bromobenzoate Chemical Properties

Melting point	18 °C
Boiling point	131 °C/14 mmHg (lit.)
density	1.403 g/mL at 25 °C (lit.)
refractive index	n20/D 1.544(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
form	clear liquid
color	Colorless to Light yellow to Light orange
Specific Gravity	1.403
Water Solubility	Insoluble
Merck	14,1408
BRN	1867129
InChIKey	XZIAFENWXIQIKR-UHFFFAOYSA-N
CAS DataBase Reference	5798-75-4(CAS DataBase Reference)
NIST Chemistry Reference	Benzoic acid, 4-bromo-, ethyl ester(5798-75-4)
EPA Substance Registry System	Benzoic acid, 4-bromo-, ethyl ester (5798-75-4)

Safety Information

Hazard Codes	Xi,N
Risk Statements	36/37/38-51/53
Safety Statements	24/25-61
RIDADR	UN 3082 9 / PGIII
WGK Germany	3
Hazard Note	Irritant
TSCA	Yes
HS Code	29163990

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

Ethyl 4-bromobenzoate Usage And Synthesis

Chemical Properties	clear colorless to yellow liquid
Uses	Ethyl 4-bromobenzoate undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.
Synthesis Reference(s)	Synthetic Communications, 22, p. 1851, 1992 DOI: 10.1080/00397919208021316Synthesis, p. 191, 1983
General Description	Ethyl 4-bromobenzoate is an ester having electron-withdrawing substituent. It undergoes reduction with potassium diisobutyl-t-butoxyaluminum hydride (PDBBA) at 0°C to yield aldehydes. Reaction of ethyl 4-bromobenzoate and substituted benzyl chloride with zinc dust and a Pd catalyst is reported.

Ethyl 4-bromobenzoate Preparation Products And Raw materials

Raw materials	Benzoic acid, 4-[[(trifluoromethyl)sulfonyl]oxy]-, ethyl ester-->2-(4-Bromophenyl)-2-oxoacetic acid-->4-Bromobenzyl alcohol-->(4-BROMO-PHENYL)-OXO-ACETALDEHYDE-->Benzenediazonium, 4-(ethoxycarbonyl)-, tetrafluoroborate(1-)-->1-CARBETHOXYIMIDAZOLE-->potassium ethyl oxalate-->4-BROMOBENZALDEHYDE DIETHYL ACETAL
Preparation Products	ETHYL 4-ACETYLBENZOATE-->4-ETHYNYL-BENZOIC ACID-->ETHYL 4-(5-FORMYL-2-FURYL)BENZOATE-->2-(4-bromophenyl)-1,3,4-oxadiazole-->ETHYL 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE-->4,4'-Bis(hydroxymethyl)biphenyl-->Ethyl 4-etoxybenzoate-->1,1,1-Trifluoro-2-hexanone

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