Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
  • CAS No.:19999-87-2
Other grades of this product :
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Basic information
Reaction
Product Name:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
Synonyms:Bis(tricyclohexylphosphine)nickel(II) chloride, 99%;Dichlorobis(tricyclohexylphosphine)nickel(II);Bis(tricyclohexylphosphine)nickel(II) Dichloride;Bis(tricyclohexylphosphine)nickel(II)chloride,99%;Bis(tricyclohexylphosphine)nickel(II) chloride,98% (PCy3)2NiCl2;Bis(tricyclohexylphosphine)dichloronickel;Dichlorobis(tricyclohexylphosphine)nickel;Bis(tricyclohexylphosphine)nickel(II) chloride,98%
CAS:19999-87-2
MF:2C18H33P.Cl2Ni
MW:690.464
EINECS:
Product Categories:Ni;metal-phosphine complexes
Mol File:19999-87-2.mol
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Chemical Properties
Melting point 227-231℃ (DEC.)
storage temp. Inert atmosphere,Room Temperature
form powder to crystal
color Yellow to Amber to Dark red
CAS DataBase Reference19999-87-2
Safety Information
Hazard Codes Xn
Risk Statements 22-40-43
Safety Statements 53-36/37-45-60
WGK Germany 3
MSDS Information
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Usage And Synthesis
Reaction
  1. An approach to five-membered lactams from aliphatic amides and terminal acetylenes by nickel catalysis.
  2. Synthesis of biaryls through nickel-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen bond cleavage.
  3. Ni-catalyzed borylation of aryl fluorides via C-F cleavage.
  4. Nickeland palladium–catalyzed coupling of aryl fluorosulfonates with aryl boronic acids enabled by sulfuryl fluoride.
  5. Nickel-catalyzed one-pot synthesis of biaryls from phenols and arylboronic acids via C-O activation using TCT reagents.
UsesCatalyst for:
  • Dehydrobrominative polycondensation
  • Arylation reactions
  • Cross-coupling
  • Suzuki-miyaura cross-coupling reactions
  • Kumada coupling of diaryl sulfates with Grignard reagents
  • Olefin dimerization
Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Preparation Products And Raw materials

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