(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

CAS No.：352655-61-9

Other grades of this product :

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Basic information

Reaction

Product Name:	(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
Synonyms:	(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
CAS:	352655-61-9
MF:	C74H104O6P2
MW:	1151.56
EINECS:
Product Categories:	Chiral Phosphine;MeOBIPHEP Series
Mol File:	352655-61-9.mol

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Chemical Properties

Boiling point	951.5±65.0 °C(Predicted)
form	crystal
color	white

Safety Information

WGK Germany	3
HS Code	29319090

MSDS Information

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Usage And Synthesis

Reaction	Rh-catalyzed reductive coupling of acetylene to aldehydes and ketones. Pt-catalyzed intramolecular hydroarylation of unactivated alkenes with indoles. Enantioselective C-C bond activation of allenyl cyclobutanes. Enantioselective ring-opening of rac-ethynyl epoxides. Enantioselective Au-catalyzed allylic alkylation of indoles with alcohols. Enantioselective Rh-catalyzed conjugate alkynylation with TMS-acetylene. Enantioselective Rh-catalyzed [3+2] annulation of aromatic ketimines. Asymmetric Rh-catalyzed Pausan-Khand reaction.
Chemical Properties	Off-white powder
Uses	Atropisomeric MeOBIPHEP ligands Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes Intramolecular ketone hydroacylation Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols Hydroamination of bicyclic alkenes and dienes with anilines 1,4-addition/asymmetric protonation of amino acrylates
General Description	sold in collaboration with Solvias AG

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny Preparation Products And Raw materials

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