3-Fluorotoluene 99%

CAS No.：352-70-5

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3-Fluorotoluene Basic information

Product Name:	3-Fluorotoluene
Synonyms:	1-fluoro-3-methyl-benzen;1-Methyl-3-fluorobenzene;3-fluoromethylbenzene;M-FLUOROTOLUENE;1-FLUORO-3-METHYLBENZENE;3-FLUOROTOLUENE;4,4-Diiso-Octanyl Diphenylamine;Fluorotoluene2
CAS:	352-70-5
MF:	C7H7F
MW:	110.13
EINECS:	206-524-8
Product Categories:	alkyl Fluorine;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;Aromatic Hydrocarbons (substituted) & Derivatives;Aryl;C7;Halogenated Hydrocarbons;Aryl Fluorinated Building Blocks;Building Blocks;C7-C8;Chemical Synthesis
Mol File:	352-70-5.mol

3-Fluorotoluene Chemical Properties

Melting point	-87 °C
Boiling point	115 °C(lit.)
density	0.991 g/mL at 25 °C(lit.)
refractive index	n20/D 1.469(lit.)
Fp	49 °F
storage temp.	Store below +30°C.
form	clear liquid
Specific Gravity	0.991
color	Colorless to Almost colorless
Water Solubility	immiscible
Merck	14,4180
BRN	1903631
LogP	2.75
CAS DataBase Reference	352-70-5(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-3-methyl-(352-70-5)
EPA Substance Registry System	m-Fluorotoluene (352-70-5)

Safety Information

Hazard Codes	F,Xi
Risk Statements	11-36/37/38
Safety Statements	16-26-36-37/39
RIDADR	UN 2388 3/PG 2
WGK Germany	2
RTECS	XT2578000
Hazard Note	Flammable/Irritant
TSCA	T
HazardClass	3
PackingGroup	II
HS Code	29036990

MSDS Information

Provider	Language
1-Fluoro-3-methylbenzene	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-Fluorotoluene Usage And Synthesis

Chemical Properties	clear colorless to light yellow liquid
Uses	3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry.
Synthesis Reference(s)	Journal of the American Chemical Society, 72, p. 4809, 1950 DOI: 10.1021/ja01166a506
General Description	A colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3---may float or sink in water.
Air & Water Reactions	Highly flammable.
Reactivity Profile	3-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.
Health Hazard	Inhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed.
Purification Methods	Purify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]

3-Fluorotoluene Preparation Products And Raw materials

Raw materials	m-Toluidine-->3-Nitrotoluene-->3-Chloro-4-(3-fluorobenzyloxy)aniline-->3-Chloro-4-(3-fluorobenzyloxy)nitrobenzene
Preparation Products	3-Fluorobenzoyl chloride-->4-Fluoro-2-methylbenzoic acid-->3-Fluorophenylacetonitrile-->2-Fluoro-4-methylaniline-->4-Fluoro-2-methylaniline-->2-Fluorotoluene-->5-Fluoro-2-nitrobenzoic acid-->3-FLUOROBENZOTRICHLORIDE-->2-Carboxy-5-fluoro-4-nitrotoluene, 5-Carboxy-2-fluoro-4-methylnitrobenzene-->3-Fluorophenylacetone-->3-FLUORO-4-IODOBENZOIC ACID-->3-Fluorobenzyl alcohol-->3-FLUORO-2-NITROTOLUENE

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