Other grades of this product :
| (-)-Taddol Basic information |
| Product Name: | (-)-Taddol | | Synonyms: | (4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE;(4R,5R)-4,5-BIS(DIPHENYLHYDROXYMETHYL)-2,2-DIMETHYL-DIOXOLANE;(-)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2,2-DIMETHYL-1,3-DIOXOLANE;(R,R)-TADDOL;(R,R)-(-)-2,3-O-ISOPROPYLIDENE-1,1,4,4-TETRAPHENYL-L-THREITOL;(-)-TADDOL;TADDOL;SEEBACH REAGENT | | CAS: | 93379-48-7 | | MF: | C31H30O4 | | MW: | 466.58 | | EINECS: | | Product Categories: | Asymmetric Synthesis;Biochemistry;Dioxanes & Dioxolanes;Dioxolanes;O-Substituted Sugars;Sugar Alcohols;chiral;Sugars;Synthetic Organic Chemistry;CHIRAL CHEMICALS;Chiral Oxygen;TADDOL Series | | Mol File: | 93379-48-7.mol |
| (-)-Taddol Chemical Properties |
| Melting point | 193-195 °C(lit.) | | alpha | -65.5 º (c=1, CHCl3) | | Boiling point | 489.39°C (rough estimate) | | density | 1.0864 (rough estimate) | | refractive index | -69 ° (C=1, CHCl3) | | storage temp. | Inert atmosphere,Room Temperature | | pka | 12.28±0.29(Predicted) | | form | Powder | | color | white | | optical activity | [α]19/D 62.6°, c = 1 in chloroform | | BRN | 3657855 | | InChIKey | RNSJHECWLNVNFE-KYJUHHDHSA-N | | CAS DataBase Reference | 93379-48-7(CAS DataBase Reference) |
| (-)-Taddol Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde | | Uses | Hydrogen-bonding organocatalyst examined in terms of acidity, deprotonation enthalpies and hydrogen bondingCatalyst involved in synthesis of cyclopropylamines via addition reactions of Grignard reagents to amidesReactant or reagent involved in:- Enantioswitching of catalytic asymmetric hydroboration
- Synthesis of derivative ligands for asymmetric hydroformylation of alkenes
- Amide-directed catalytic asymmetric hydroboration of trisubstituted alkenes
- Addition of deactivated alkyl Grignard reagents to aldehydes
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| (-)-Taddol Preparation Products And Raw materials |
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