Methoxyethene

Methoxyethene
  • CAS No.:107-25-5
Other grades of this product :
Methoxyethene Basic information
Product Name:Methoxyethene
Synonyms:1-Methoxyethylene;agrisynthmve;CH2=CHOCH3;Ethene,methoxy-;VINYL METHYL ETHER;Vinyl methyl ether,inhibited;METHYL VINYL ETHER;Vinl methyl ether,inhibited
CAS:107-25-5
MF:C3H6O
MW:58.08
EINECS:203-475-4
Product Categories:
Mol File:107-25-5.mol
Methoxyethene Chemical Properties
Melting point -122°C
Boiling point 6°C
density 0.7440
vapor pressure 169.17kPa at 20℃
refractive index 1.3947
Water Solubility 17.1g/L at 25℃
LogP0.42 at 25℃
CAS DataBase Reference107-25-5(CAS DataBase Reference)
NIST Chemistry ReferenceEthene, methoxy-(107-25-5)
EPA Substance Registry SystemVinyl methyl ether (107-25-5)
Safety Information
Hazard Codes F+
Risk Statements 12
Safety Statements 9-16-33
RIDADR UN 1087
HazardClass 2.1
Hazardous Substances Data107-25-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Methoxyethene English
Methoxyethene Usage And Synthesis
Chemical PropertiesColorless compressed gas, or colorless liquid. Slightly soluble in water; soluble in alcohol and ether; easily polymerized. Commercial material contains a small proportion of polymerization inhibitor.
UsesMethyl Vinyl Ether is a reagent in the preparation of sodium alginate interpolymer complexes, pH-tunable drug carries.
UsesCopolymers used in coatings and lacquers; modifier for alkyl, polystyrene, and ionomer resins; plasticizer for nitrocellulose and adhesives.
General DescriptionA colorless gas with a sweet odor. Shipped as a liquefied gas under own vapor pressure. Contact with the liquid may cause frostbite. Easily ignited. Vapors are heavier than air. Leaks may either be liquid or vapor. May asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat containers may rupture violently and rocket.
Air & Water ReactionsHighly flammable. Reacts slowly with water to form acetaldehyde, reaction is not hazardous unless water is hot or acids are present. Form dangerous peroxides when exposed to air.
Reactivity ProfileMethoxyethene reacts vigorously with oxidizing materials. Explosive in the form of vapor when exposed to heat, flame or strong oxidizing agents. Reacts, possibly explosively with halogens (bromine, chlorine) or hydrogen halides (hydrogen bromide, hydrogen chloride) [Baker, 1980, p. 487]. On contact with dilute acids or even mildly acidic solids (calcium chloride, ceramics) undergoes rapid, exothermic homopolymerization, which cannot be prevented by antioxidants. Must be stored in the presence of base [MVE Brochure, Billingham, ICI, 1962].
Health HazardInhalation causes intoxication, blurring of vision, headache, dizziness, excitation, loss of consciousness. Liquid or concentrated vapor irritates eyes and causes frostbite of skin. Aspiration of the liquid will cause chemical pneumonitis.
Fire HazardBehavior in Fire: Containers may explode. Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.
Flammability and ExplosibilityExtremelyflammable
Safety ProfileMildly toxic by ingestion. A very dangerous fire hazard when exposed to heat, flame, or oxiduers. Explosive in the form of vapor when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, stop flow of gas. Potentially explosive reaction with halogens (e.g., bromine, chlorine) or hydrogen halides (e.g., hydrogen bromide, hydrogen chloride). Reaction with acids forms acetaldehyde. Weak acids catalyze the exothermic polymerization of the ether. The unstabilized ether can form dangerous peroxides. When heated to decomposition it emits acrid smoke and irritating fumes.

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