Other grades of this product :
| DIIODOTRIPHENYLPHOSPHORANE Basic information |
| Product Name: | DIIODOTRIPHENYLPHOSPHORANE | | Synonyms: | DIIDOTRIPHENYLPHOSPHORANE;DIIODOTRIPHENYLPHOSPHORANE;TRIPHENYLPHOSPHINE DIIODIDE;diiodotriphenyl-phosphoran;iodotriphenylphosphoraniumiodide;DIIODOTRIPHENYLPHOSPHORANE, TECH., 90%;Triphenyldiiodophosphorane;diiodo(triphenyl)-$l^{5}-phosphane | | CAS: | 6396-07-2 | | MF: | C18H15I2P | | MW: | 516.09 | | EINECS: | | Product Categories: | | Mol File: | 6396-07-2.mol |
| DIIODOTRIPHENYLPHOSPHORANE Chemical Properties |
| Melting point | 210-220 °C (lit.) | | storage temp. | 2-8°C | | form | Powder | | color | Yellow to orange | | Sensitive | Light Sensitive | | CAS DataBase Reference | 6396-07-2 |
| DIIODOTRIPHENYLPHOSPHORANE Usage And Synthesis |
| Uses | Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent: - To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide.
- To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine.
- In the synthesis of alkyl nitrates from alcohols.
- In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime.
- For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine.
Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions. |
| DIIODOTRIPHENYLPHOSPHORANE Preparation Products And Raw materials |
|
日本语
한국어
Français
Deutsch
España
Türkiye