4-NITROCINNAMALDEHYDE

4-NITROCINNAMALDEHYDE
  • CAS No.:1734-79-8
Other grades of this product :
4-NITROCINNAMALDEHYDE Basic information
Product Name:4-NITROCINNAMALDEHYDE
Synonyms:4-NITROCINNAMALDEHYDE;3-(4-NITROPHENYL)-2-PROPENAL;PARA-NITROCINNAMALDEHYDE;p-Nitrocinnamaldehyde,98%;4-Nitrobenzeneacrylaldehyde;4-Nitrobenzenepropenal;3-(4-Nitrophenyl)acrylaldehyde 3-(4-Nitrophenyl)-2-propenal;3-(4-Nitrophenyl)acrylaldehyde
CAS:1734-79-8
MF:C9H7NO3
MW:177.16
EINECS:217-076-8
Product Categories:Aromatic Aldehydes & Derivatives (substituted)
Mol File:1734-79-8.mol
4-NITROCINNAMALDEHYDE Chemical Properties
Melting point 140-143 °C(lit.)
Boiling point 309.06°C (rough estimate)
density 1.3312 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Inert atmosphere,Store in freezer, under -20°C
Water Solubility Insoluble in water.
Sensitive Air Sensitive
BRN 1565424
CAS DataBase Reference1734-79-8(CAS DataBase Reference)
EPA Substance Registry System2-Propenal, 3-(4-nitrophenyl)- (1734-79-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-36
WGK Germany 3
RTECS GD6650000
TSCA Yes
HS Code 29130000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4-NITROCINNAMALDEHYDE Usage And Synthesis
Chemical Propertiesbeige to yellow-brown crystals or cryst. powder
UsesDoebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

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