[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE

CAS No.：127593-28-6

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[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Basic information

Reaction

Product Name:	[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
Synonyms:	[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE;PALLADIUM, [(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[DIPHENYLPHOSPHINE-.KAPPA.P]]DICHLORO-, (SP-4-2)-;REF DUPL: [(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium (II) chloride;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),Min.98%;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),98% (S-BINAP)PdCl2;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLADIUM(II) CHLORIDE;[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
CAS:	127593-28-6
MF:	C44H34Cl2P2Pd
MW:	802.02
EINECS:	631-388-5
Product Categories:	Pd
Mol File:	127593-28-6.mol

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Chemical Properties

Melting point	>300°C
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
InChIKey	VDHAUMFISVWIRX-UHFFFAOYSA-L
CAS DataBase Reference	127593-28-6

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-37/39
WGK Germany	3

MSDS Information

Provider	Language
SigmaAldrich	English

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Usage And Synthesis

Reaction

Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.
Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Preparation Products And Raw materials

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