BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE

BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
  • CAS No.:56183-63-2
Other grades of this product :
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Basic information
Product Name:BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE
Synonyms:Bis(di-i-propylamino)chlorophosphine, 97+%;Chlorobis(N,N-diisopropylamino)phosphine;Tetraisopropylphosphorodiamidous chloride;diisopropylaMino)phosphine;1-chloro-N,N,N',N'-tetraisopropylphosphinediaMine;Bis(diisopropylaMino)chlorophosphine >=95.0%;BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE;BIS(DI-I-PROPYLAMINO)CHLOROPHOSPHINE
CAS:56183-63-2
MF:C12H28ClN2P
MW:266.79
EINECS:
Product Categories:Achiral Phosphine;Alkyl Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphorus Compounds;P-Cl;Phosphorus Precursors;organophosphine halide
Mol File:56183-63-2.mol
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Chemical Properties
Melting point 100-104 °C(lit.)
Boiling point 291℃
Fp 130℃
form Powder
pka4.50±0.70(Predicted)
color white to off-white
Sensitive air sensitive, moisture sensitive
CAS DataBase Reference56183-63-2(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 14-34
Safety Statements 26-27-28-36/37/39-45
RIDADR UN 3261 8/PG 1
WGK Germany 3
HazardClass 8
PackingGroup II
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesBis(diisopropylamino)chlorophosphine has been used in the synthesis of tert-butyl tetraisopropylphosphorodiamidite ligand for palladium-catalyzed Buchwald–Hartwig amination reaction.It is also can be used to synthesize:
  • acyclic N-phosphonio imine catalyst for selective epoxidations
  • boryl-substituted methylenephosphonium derivatives
BIS(DIISOPROPYLAMINO)CHLOROPHOSPHINE Preparation Products And Raw materials
Raw materialsDiethyl ether-->Sodium-->Hexane-->Acetonitrile-->Phosphorus trichloride-->Diisopropylamine

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