Product

Di-tert-butylchlorophosphane

CAS No.：13716-10-4

Other grades of this product :

Di-tert-butylchlorophosphane Basic information

Product Name:	Di-tert-butylchlorophosphane
Synonyms:	AURORA KA-1319;Bis(1,1-dimethylethyl)-phosphinous chloride;DI-T-BUTYLCHLOROPHOSPHINE;DI-T-BUTYLPHOSPHINOUS CHLORIDE;DI-TERT-BUTYLPHOSPHORUS CHLORIDE;DI-TERT-BUTYLCHLOROPHOSPHANE;DI-TERT-BUTYLCHLOROPHOSPHINE;DI-TERT-BUTYLCHLOROPHO
CAS:	13716-10-4
MF:	C8H18ClP
MW:	180.66
EINECS:
Product Categories:	organophosphine halide;Catalysis and Inorganic Chemistry;Ligand;Phosphorus Compounds;Phosphorus Precursors;Phosphines;Chlorophosphines;Achiral Phosphine;Alkyl Phosphine;P-Cl
Mol File:	13716-10-4.mol

Di-tert-butylchlorophosphane Chemical Properties

Melting point	2-3°C
Boiling point	48 °C/3 mmHg (lit.)
density	0.951 g/mL at 25 °C (lit.)
refractive index	n20/D 1.482(lit.)
Fp	142 °F
solubility	Miscible with terahydrofuran.
form	Liquid
Specific Gravity	0.951
color	Clear colorless
Sensitive	Air & Moisture Sensitive
InChIKey	MCRSZLVSRGTMIH-UHFFFAOYSA-N
CAS DataBase Reference	13716-10-4(CAS DataBase Reference)
NIST Chemistry Reference	Phosphinous chloride, bis(1,1-dimethylethyl)-(13716-10-4)

Safety Information

Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45-25
RIDADR	UN 3265 8/PG 2
WGK Germany	3
TSCA	No
HazardClass	8
PackingGroup	II
HS Code	29310099

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

Di-tert-butylchlorophosphane Usage And Synthesis

Chemical Properties	Colorless to light yellow liqui
Uses	Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.
Uses	Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis.
Uses	Bulky ligand used with Pd(OAc)₂ in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
Application	Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.
Precautions	Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Di-tert-butylchlorophosphane Preparation Products And Raw materials

Raw materials	Tetrahydrofuran-->Sodium-->Nitrogen-->Magnesium-->Phosphorus trichloride-->Pentane-->tert-Butyllithium-->2-Chloro-2-methylpropane
Preparation Products	1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,-->1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE-->DI-T-BUTYLMETHYLPHOSPHINE-->1-DIPHENYLPHOSPHINO-1'-(DI-TERT-BUTYLPH&-->RAC-2-(DI-T-BUTYLPHOSPHINO)-1,1'-BINAPHTHYL-->2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&-->DI-T-BUTYLNEOPENTYLPHOSPHINE, MIN. 95-->1,3-BIS(DI-T-BUTYLPHOSPHINOMETHYL)BENZENE-->PNN-->DI-TERT-BUTYLPHENYLPHOSPHINE

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