2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos

2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98%  t-butylBrettPhos
  • CAS No.:1160861-53-9
Other grades of this product :
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos Basic information
Reaction
Product Name:2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos
Synonyms:-3,6-dimethoxybiphenyL;2-(Di-tert-butylphosphino)-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl;2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (t-BuBrettPhos);tBuBrettPhos 97%;tBuBrettPhos;tertButylBrettPhos;tert-ButylBrettPhos;t-butylBrettPhos
CAS:1160861-53-9
MF:C31H49O2P
MW:484.69
EINECS:
Product Categories:Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:1160861-53-9.mol
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos Chemical Properties
Melting point 166-170°C
Boiling point 534.9±50.0 °C(Predicted)
form crystal
color white
InChIKeyREWLCYPYZCHYSS-UHFFFAOYSA-N
Safety Information
WGK Germany 3
MSDS Information
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos Usage And Synthesis
Reaction
  1. Ligand used in the Pd-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.
  2. Ligand used in the Pd-catalyzed O-arylation of ethyl acetohydroximates.
  3. Ligand used in the Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
  4. Ligand used in the Pd-catalyzed cross-coupling of amides and aryl mesylates.
UsesBuchwald Phosphine Ligands for chemical Synthesis
General DescriptiontBuBrettPhos is a dialkylbiaryl phosphine ligand developed by the Buchwald group. It promotes cross-coupling reactions more efficiently and exhibits improved reactivity compared to other catalytic systems.
2-(Di-t-butylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% t-butylBrettPhos Preparation Products And Raw materials

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