2-Benzylaminopyridine

2-Benzylaminopyridine
  • CAS No.:6935-27-9
Other grades of this product :
2-Benzylaminopyridine Basic information
Product Name:2-Benzylaminopyridine
Synonyms:BENZYL-PYRIDIN-2-YL-AMINE;AURORA KA-4160;ALPHA-BENZYLAMINOPYRIDINE;n-(phenylmethyl)-2-pyridinamin;N-(2-Pyridine)benzylamine;N-Benzyl-2-pyridinamine;N-Benzyl-2-pyridylamine~N-(2-Pyridyl)benzylamine;2-BENZYLAMINOPYRIDINE
CAS:6935-27-9
MF:C12H12N2
MW:184.24
EINECS:230-060-5
Product Categories:Pyridines derivates;C9 to C46;Heterocyclic Building Blocks;Pyridines
Mol File:6935-27-9.mol
2-Benzylaminopyridine Chemical Properties
Melting point 95-97 °C (lit.)
Boiling point 116-131 °C/0.6 mmHg (lit.)
density 1.1160 (rough estimate)
refractive index 1.6266 (estimate)
Fp 182°C/12mm
storage temp. Sealed in dry,2-8°C
form powder to crystal
pka6.61±0.10(Predicted)
color White to Light yellow to Light orange
BRN 134309
CAS DataBase Reference6935-27-9(CAS DataBase Reference)
EPA Substance Registry System2-Pyridinamine, N-(phenylmethyl)- (6935-27-9)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-37/38-41-40-36/37/38-20/21/22
Safety Statements 26-39-36-22
WGK Germany 3
RTECS US2700000
TSCA Yes
HS Code 29333999
MSDS Information
ProviderLanguage
2-Benzylaminopyridine English
SigmaAldrich English
ACROS English
ALFA English
2-Benzylaminopyridine Usage And Synthesis
Chemical Propertieswhite to off-white powder
Uses2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.
Synthesis Reference(s)Organic Syntheses, Coll. Vol. 4, p. 91, 1963The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z
General Description2-Benzylaminopyridine on reaction with BBr3 yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).

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